Heat of neutralisation of NH4OH and HCl is from Chemistry Equili

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 Multiple Choice QuestionsMultiple Choice Questions

561.

In the formation of SO3 according to following equilibrium 2SO2 + O2  2SO3 + heat, which conditions favour the formation of SO3?

  • Low pressure

  • Low concentration of oxygen

  • Low temperature and use of catalyst

  • High temperature without using catalyst


562.

Which of the following mixtures forms an acid buffer?

  • NaOH + HCl

  • CH3COOH + CH3COONa

  • NH4OH + NH4Cl

  • H2CO3 + (NH4)2CO3


563.

When NH4Cl is added to NH4OH solution, the dissociation of ammonium hydroxide is reduced. It is due to

  • common ion effect

  • hydrolysis

  • oxidation

  • reduction


564.

Strongest Bronsted base among the following anions is

  • ClO-

  • ClO2-

  • ClO3-

  • ClO4-


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565.

pH of a solution is 4. The hydroxide ion concentration of the solution would be

  • 10-4

  • 10-10

  • 10-2

  • 10-12


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566.

Heat of neutralisation of NH4OH and HCl is

  • equal to 13.7 kcal

  • more than 13.7 kcal

  • less than 13.7 kcal

  • more than one is correct


C.

less than 13.7 kcal

Heat of neutralisation of strong acid and strong base is always constant (i e., 13.7 kcal). If acid or base is weak, heat of neutralisation is always less than 13.7 kcal because weak acid or base does not ionises completely, for complete ionisation of weak acid or base some energy is required which is used from heat  of neutralisation.

NH4OH is weak base and HCl is strong acid, so value of heat of neutralisation is less than 13.7 kcal.


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567.

A chemical reaction is in equilibrium when

  • the reactants are completely transformed into products

  • the rate of forward reaction is equal to the rate of backward reaction

  • the formation of products is minimised

  • equal amount of reactants and products are present


568.

For the following gaseous reaction, H2 + I2HI, the equilibrium constant

  • Kp > Kc

  • Kp< Kc

  • Kp= Kc

  • Kp= 1/Kc


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569.

According to Le-Chatelier's principle which of the following factors influence a chemical system?

  • Concentration only

  • Pressure only

  • Temperature only

  • Concentration, pressure and temperature


570.

The pH of water decreases with?

  • increase in temperature

  • increase in pressure

  • decrease in temperature

  • decrease in pressure


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