In the equilibrium reaction 2HI (g) H2 + I2 which of the following expressions is true?
Kp = Kc
Kc = 2Kp
Kp > Kc
Kc = Kp (RT)2
1.1 moles of A and 2.2 moles of B are mixed in a container of one litre volume to obtain the equilibrium A + 2B 2C + D.
At equilibrium 0.2 moles of C are formed. The equilibrium constant for the above reaction is
0.001
0.002
0.003
0.004
In which solution/ solvent the solubility of AgCl is minimum?
0.01 M NaCl
0.01 M CaCl2
Pure water
0.001 M AgNO3
Which one of the following salts gives an acidic solution in water?
CH3COONa
NH4Cl
NaCl
CH3COONH4
The chemical decomposition of XY2 occurs as . The initial vapour pressure of XY2 is 600 mm of mercury and at equilibrium it is 800 mm of mercury. Find out the value of K for this reaction when the volume of the system remains constant.
50
100
166.6
150
The degree of ionisation of decinormal solution of CH3COOH is 1.3%. If the log of 1.3 is 0.11, the pH of this solution is
2.89
3.89
4.89
0.89
A buffer solution is obtained by mixing 10 mL of 1.0M CH3COOH and 20mL of 0.5M CH3COONa and it is diluted to 100mL using distilled water. pKa of CH3COOH is 4.76. The pH of this buffer solution is
2.76
3.76
4.76
0.76
1.0 L of 1.0 M solution of sodium hydroxide is neutralised by 1.0 L of 1.0 M of methanoic acid. If the heat of formation of water is X, the neutralisation energy of above reaction is
less than X
more than X
equal to X
None of the above
A.
less than X
The heat of neutralisation of a strong acid against a strong base is always constant (13.7 kcal).
H+ + OH- H2O , ΔH = 13.7 kcal
In case of neutralisaton of weak acid (methanoic acid) against a strong base (sodium hydroxide), since a part of the evolved heat is used up in ionising the weak acid. Thus, it is always less than 13.7 kcal mol-1 (i.e., X).