The reaction quotient 'Q' is useful in predicting the direction of the reaction. Which of the following is incorrect?
If Qc < Kc, the forward reaction is favoured
If Qc > Kc, the forward reaction is favoured
If Qc >Kc, the forward reaction is favoured and Qc =Kc, no reaction occur.
None of these
Equivalent weight of an acid :
depends on the reaction involved
depends upon the number of oxygen atoms present
is always constant
None of the above
Two moles of PCl5 were heated in a closed vessel of 2 L. At equilibrium, 40% of PCl5 is dissociated into PCl3 and Cl3. The value of equilibrium constant is :
0.53
0.267
2.63
5.3
The solubility product of Barium sulphate is 1.5 × 10-9 at 18°C. Its solubility in water at 18°C is :
1.5 × 10-9
1.5 × 10-5
3.9 × 10-9
3.9 × 10-5
D.
3.9 × 10-5
Let solubility of BaSO4 = x mol/ L
Ions at equilibrium
Ksp = [Ba2+][SO]
= x × x
= x2
Given,
Ksp = 1.5 × 10-9
(1.5 × 10-9) = x2
or, = x
or, x = 3.9 × 10-5 mol/ L
Which one of the following is called amphoteric solvent ?
Ammonium hydroxide
Chloroform
Benzene
Water
100 mL of 0.04 N HCl aqueous solution is mixed with 100 mL of 0.02 N NaOH solution. The pH of the resulting solution is
1.0
1.7
2.0
2.3
If a system is at equilibrium, the rate of forward to the reverse reaction is :
less
equal
high
at equilibrium
The equilibrium constant for the reaction N2(g) + O2(g) 2NO(g) is 4×10-4 at 200K. In presence of a catalyst the equilibrium is attained ten times faster. Therefore the equilibrium constant in presence of catalyst 2000 K is
4×10-3
4×10-2
40×10-4
4×10-4