The standard emf of a cell, involving one electron change is found to be 0.591 V at 25°C. The equilibrium constant of the reaction is (F = 96500 C mol-1)
1.0 × 101
1.0 × 105
1.0 × 1010
1.0 × 1030
At a certain temperature, the solubility of the salt, MmAn in water is s mol/L. The solubility product of the salt is
MmAn
(m + n)sm + n
mmnnsm + n
mmAns
C.
mmnnsm + n
MmAn (s) →
Ksp = [Mn+]m[Am+]n
= (ms)m(ns)n
= mmnn(s)m + n
The pKa value of (I) 2 - bromo propanoic acid, (II) 2-fluoro propanoic acid, (III) 3 - fluoro propanoic acid, (IV) 3- bromo propanoic acid decreases as
I > III > IV > II
II > IV > III > I
I > IV > III > II
IV > I > III > II