Equilibrium constants K1 and K2 for the following equilibriaNO (g

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 Multiple Choice QuestionsMultiple Choice Questions

851.

A 0.1 aqueous solution of a weak acid is 2% ionised. If the ionic product of water is 1 x 10-4, the [OH-] is

  • 5 x 10-12 M

  • 2 x 10-3 M

  • 1 x 10-14 M

  • None of these


852.

Disperse phase and dispersion medium in butter are respectively

  • solid and liquid

  • liquid and solid

  • liquid and liquid

  • solid and solid


853.

9.2 g N2O4 is heated in a 1L vessel till equilibrium state is established

N2O4 (g)  2NO2 (g)

In equilibrium state 50% Np4 was dissociated, equilibrium constant will be (mol. wt. of N2O4 = 92)

  • 0.1

  • 0.4

  • 0.3

  • 0.2


854.

Solubility product of PbCl2 at 298 K is 1 x 10-6. At this temperature solubility of PbCl2 in mol/L is

  • (1 x 10-6)1/2

  • (1 x 10-6)1/3

  • (0.25 x 10-6)1/3

  • (2.5 x 10-6)1/2


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855.

Which of the following is the electron deficient molecule?

  • B2H6

  • C2H6

  • PH3

  • SiH4


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856.

Equilibrium constants K1 and K2 for the following equilibria
NO (g) + 12O2  K1 NO2(g) and

2NO2(g) K2 2NO (g) + O2(g)

are related as

  • K2 = 1 K1

  • K2 = K12

  • K2 = K12

  • K2 =1K12


D.

K2 =1K12

(i) NO (g) + 12O2 (g) K1 NO2(g)

 So, K1[NO2][NO] [O2]12          ...(1)

(ii) 2NO2 (g) K2 2NO + O2 (g)

So, K2[NO]2 [O2][NO2]             ...(2)

From equation (1)

K12 = [NO2]2[NO2]  or

1K12 = [NO]2 [O2][NO2]2              ...(3)

from equation (2) and (3)

K21K12


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857.

H2S gas when passed through a solution of cations containing HCl precipitates the cations of second group of qualitative analysis but not those belonging to the fourth group. It is because: 

  • presence of HCl decreases the sulphide ion concentration

  • presence of HCl increases the sulphide ion concentration

  • solubility product of group II sulphides is more than that of group IV sulphides

  • sulphides of group IV cations are unstable in HCl


858.

A + B C + D. If initially the concentration of A and B are both equal but at equilibrium, concentration of D will be twice of that of A, then what will be the equilibrium constant of reaction?

  • 4/9

  • 9/4

  • 1/9

  • 4


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859.

Given pH of a solutionA is 3 and it is mixed with another solution B having pH 2. If both mixed, then resultant pH of the solution will be :

  • 3 : 2

  • 1 : 9 

  • 3 : 4

  • 3 : 5


860.

When NaNO3 is heated in a closed vessel oxygen is liberated and NaNO3 is left behind,

At equilibrium:

  • addition of NaNO2 favours reverse reaction

  • addition of NaNO3 favours reverse reaction

  • increasing temperature favours forward reaction

  • decreasing temperature favours backward reaction


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