A 0.1 aqueous solution of a weak acid is 2% ionised. If the ionic product of water is 1 x 10-4, the [OH-] is
5 x 10-12 M
2 x 10-3 M
1 x 10-14 M
None of these
Disperse phase and dispersion medium in butter are respectively
solid and liquid
liquid and solid
liquid and liquid
solid and solid
9.2 g N2O4 is heated in a 1L vessel till equilibrium state is established
N2O4 (g) 2NO2 (g)
In equilibrium state 50% Np4 was dissociated, equilibrium constant will be (mol. wt. of N2O4 = 92)
0.1
0.4
0.3
0.2
Solubility product of PbCl2 at 298 K is 1 x 10-6. At this temperature solubility of PbCl2 in mol/L is
(1 x 10-6)1/2
(1 x 10-6)1/3
(0.25 x 10-6)1/3
(2.5 x 10-6)1/2
Equilibrium constants K1 and K2 for the following equilibria
NO (g) + NO2(g) and
2NO2(g) 2NO (g) + O2(g)
are related as
H2S gas when passed through a solution of cations containing HCl precipitates the cations of second group of qualitative analysis but not those belonging to the fourth group. It is because:
presence of HCl decreases the sulphide ion concentration
presence of HCl increases the sulphide ion concentration
solubility product of group II sulphides is more than that of group IV sulphides
sulphides of group IV cations are unstable in HCl
A.
presence of HCl decreases the sulphide ion concentration
H2S gas is passed in presence of HCl, in qualitative analysis of cation of second group, therefore, due to common ion effect, lower concentration of sulphide ions is obtained which is sufficient for the precipitation of second group cations in form of their sulphides due to lower value of their solubility product (Ksp). Here, fourth group cations are not precipitated because they require for exceeding their ionic product to their solubility products and higher sulphide ions concentration due to their higher Ksp which is not obtained here due to common ion effect.
A + B C + D. If initially the concentration of A and B are both equal but at equilibrium, concentration of D will be twice of that of A, then what will be the equilibrium constant of reaction?
4/9
9/4
1/9
4
Given pH of a solutionA is 3 and it is mixed with another solution B having pH 2. If both mixed, then resultant pH of the solution will be :
3 : 2
1 : 9
3 : 4
3 : 5
When NaNO3 is heated in a closed vessel oxygen is liberated and NaNO3 is left behind,
At equilibrium:
addition of NaNO2 favours reverse reaction
addition of NaNO3 favours reverse reaction
increasing temperature favours forward reaction
decreasing temperature favours backward reaction