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 Multiple Choice QuestionsMultiple Choice Questions

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471.

An unknown alcohol is treated with the “Lucas reagent” to determine whether the alcohol is primary, secondary or tertiary. Which alcohol reacts fastest and by what mechanism

  • Secondary alcohol by SN1

  • Tertiary alcohol by SN1

  • Secondary alcohol by SN2

  • Secondary alcohol by SN2

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472.

What is DDT among the following

  • Greenhouse gas 

  • A fertilizer

  • Biodegradable pollutant

  • Biodegradable pollutant

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473.

2–Hexyne gives trans–2–Hexene on treatment with

  • Pt/H2

  • Li/NH3

  • Pd/BaSO4

  • Pd/BaSO4

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474.

In the given transformation, which of the following is the most appropriate reagent?

  • NH2NH2,O-H

  • Zn − Hg/HCl

  • Na,Liq.NH3

  • Na,Liq.NH3

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475.

Sodium ethoxide has reacted with ethanoyl chloride. The compound that is produced in the above reaction is

  • Diethyl ether

  • 2-Butanone

  • Ethyl chloride

  • Ethyl chloride

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476.

Consider the following bromides:



The correct order of SN1 reactivity is 

  • A > B > C

  • B > C > A

  • B > A > C

  • B > A > C

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477.

The increasing order of the reactivity of the following halides for the SN1 reaction is

  • (III) < (II) < (I) 

  • (II) < (I) < (III)

  • (I) < (III) < (II)

  • (I) < (III) < (II)

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478.

3-Methyl-pent-2-ene on reaction with HBr in presence of peroxide forms an addition product.The number of possible stereoisomers for the product is

  • Six

  • Two

  • Zero

  • Zero

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479.

The major product obtained in the following reaction is



  • C6H5CH (OtBu) CH2C6H5

  • C6H5CH=CHC6H5

  • (+)C6H5CH(OtBu)CH2H5

  • (+)C6H5CH(OtBu)CH2H5

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480.

Arrange the carbanions left parenthesis CH subscript 3 right parenthesis subscript 3 comma space straight C subscript 6 straight H subscript 5 straight C with minus on top straight H subscript 2 space comma thin space straight C with minus on top Cl subscript 3 comma space left parenthesis CH subscript 3 right parenthesis subscript 2 space straight C with minus on top straight H  in order of their decreasing stability 

  • straight C subscript 6 straight H subscript 5 straight C with minus on top straight H subscript 2 space greater than space straight C with minus on top Cl subscript 3 space greater than thin space left parenthesis CH subscript 3 right parenthesis subscript 3 straight C with minus on top space greater than thin space left parenthesis CH subscript 3 right parenthesis subscript 2 straight C with minus on top straight H
  • thin space left parenthesis CH subscript 3 right parenthesis subscript 2 straight C with minus on top straight H greater than space straight C with minus on top Cl subscript 3 space greater than straight C subscript 6 straight H subscript 5 straight C with minus on top straight H subscript 2 greater than thin space left parenthesis CH subscript 3 right parenthesis subscript 3 straight C with minus on top space
  • space straight C with minus on top Cl subscript 3 space greater than straight C subscript 6 straight H subscript 5 straight C with minus on top straight H subscript 2 greater than thin space left parenthesis CH subscript 3 right parenthesis subscript 2 straight C with minus on top straight H greater than thin space left parenthesis CH subscript 3 right parenthesis subscript 3 straight C with minus on top space
  • space straight C with minus on top Cl subscript 3 space greater than straight C subscript 6 straight H subscript 5 straight C with minus on top straight H subscript 2 greater than thin space left parenthesis CH subscript 3 right parenthesis subscript 2 straight C with minus on top straight H greater than thin space left parenthesis CH subscript 3 right parenthesis subscript 3 straight C with minus on top space
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