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 Multiple Choice QuestionsShort Answer Type

91. When 2-chloro-3-methyl butane is treated with alcoholic potash, 2-methyl-2-butene is the main product. Give reason.
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92.

Hydrogen atom of chloroform is definitely acidic, but that of methane is not. Why?

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93.

What is the role of phosphorus in the preparation of ethyl iodide from ethyl alcohol and iodine?

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94.

tetra - Butyl iodide undergoes following reactions:

(CH3)3 Cl+H2O → (CH3)3COH + HI
(CH3)3CI + OH → (CH3)2 C = CH2 + H2O + I 

Give reasons.

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95. p-Dichlorobenzenes have higher melting points and lower solubilities than that of their o- and m-isomers. Why?
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96.

RBr reacts with AgNO2 to give both RNO2 and RONO. Give reason.

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97.

Why a small amount of ethyl alcohol is added to chloroform stored for use as an anaes-thatic?


To convert any carbonyl chloride formed into harmless ethyl carbonate.
2C2H5OH + COCl2 → (C2H5)2CO3 + 2HCl

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98.

After using carbon tetrachloride as a fire extinguisher inside a closed space, the space is thoroughly ventilated. Why?

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99.

Unlike the chlorine atom in CH3CI, that in chlorobenzene, C6H5Cl, is not easily replaced by the —OH group. Give reason.

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100.

When a iodoform is heated with silver nitrate solution, a precipitate is formed. No precipitate is formed if chloroform is used in place of iodoform. Why?

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