Excess of copper in toxic proportions in plants/animals can be removed by chelating with
EDTA
ethane-1,2-diamine
oxalate ion
D-pencillamine
Which will undergo SN2 reaction fastest among the following halogen compounds?
CH3CH2F
CH3CH2Cl
CH3CH2Br
CH3CH2I
D.
CH3CH2I
SN2 reactions involve the formation of intermediate transition state, thus less hindered alkyl halide readily undergoes this reaction.
Moreover, C-I bond is less stable than C-Br or C-Cl bond, thus alkyl iodides are more reactive as compared to other halides. Hence, CH3CH2I is most reactive towards SN2 reaction.
The alkyl halide that undergoes SN1 reaction more readily is
t-butyl bromide
n-propyl bromide
vinyl bromide
isopropyl bromide
An alkyl halide (R X) reacts with Na to form 4, 5-diethyloctane. Compound R X is
CH3(CH2)3Br
CH3(CH2)2CH(Br)CH2CH3
CH3(CH2)3CH(Br)CH3
CH3(CH2)5Br
Which of the following is a double base propellant ?
Methyl nitrate and nitromethane
Nitroglycerine and nitrocellulose
Kerosine and alcohol
Acrylic rubber and liquid N2O4
Which one of the following compounds is capable of existing in a mesa form?
2,4-dibromopentane
3,3-dibromopentane
4-bromo-2-pentanol
3-bromo-2-pentanol
Which of the following is not true of carbanions?
The carbon carrying the charge has eight valence electrons
They are formed by heterolytic fission
They are paramagnetic
The carbon carrying the charge is sp3 hybridised
The SN1 reactivity of the following halides will be in the order
(i) (CH3)3CBr
(ii) (C6H5)2CHBr
(iii) (C6H5)2C(CH3)Br
(iv) (CH3)2CHBr
(v) C2H5Br
(iii) > (ii) > (i) > (iv) > (v)
(v) > (iv) > (i) > (ii) > (iii)
(ii) > (i) > (iii) > (v) > (iv)
(v) > (i) > (ii) > (iv) > (iii)
Which of the following does not answer iodoform test?
n-butyl alcohol
sec-butyl alcohol
Acetophenone
Acetaldehyde
Aniline on treatment with NaNO2 in HCl at 0°C followed by treatment with alkaline β-naphthol gives:
a violet solution
a red solution
a green solution
a blue precipitate