The reaction between an alkyl halide and sodium metal in dry ethe

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 Multiple Choice QuestionsMultiple Choice Questions

571.

Match the following lists
List I List II
(A) Benzene 1. Phosegen
(B) Ethylene 2. Silver mirror
(C) Acetaldehyde 3. Mustard gas
(D) Chloroform 4. (4n+2)Π electron
  5.Carbylamine

The correct answer is

  • A B C D

    4 3 2 1

  • A B C D

    3 2 1 4

  • A B C D

    2 4 5 3

  • A B C D

    5 1 4 3


572.

Match the following lists:
List- I List- II
A. Grignard reagent 1. H2/ Pd-BaSO4
B. Clemmensen reduction 2. N2H4 | KOH | (CH2)2-OH
C. Rosenmund reduction 3. CH3Mg X
D. Wolff-Kishner reduction

4. Zn-Hg | conc. HCl

5. H2| Ni

  • A - 3; B - 4; C - 2; D - 1

  • A - 3; B - 4; C - 1; D - 2

  • A - 2; B - 1; C - 4; D - 5

  • A - 5; B - 3; C - 2; D - 1


573.

The pairs 2R, 3R-butane diol and 2S, 3S-butane diol are enantiomeric.

  • 2R, 3R and 2S, 3S

  • 2S, 3S and 2S, 3R

  • 2R, 3R and 2R, 3S

  • 2S, 3S and 2R, 3S


574.

The two enantiomers of secondary butyl chloride differ from each other in which one of the following properties?

  • Boiling point

  • Specific rotation

  • Density

  • Cl—Cl bond length


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575.

Assertion (A) : Cyclohexane is the most stable cycloalkane.

Reason (R) : Cyclopropane and cyclobutane are less stable due to angle starin and torsional strain.

The correct answer is-

  • Both (A) and (R) are true but (R) is not the correct explanation of (A).

  • (A) is true but (R) is not true.

  • (A) is not true but (R) is true.

  • Both (A) and (R) are true and (R) is the correct explanation of (A).


576.

Identify X and Y in the following reactions-


577.

This reaction is known as

  • Wurtz-Fittig reaction

  • Wurtz reaction

  • Fittig reaction

  • Friedel-Crafts reaction


578.

Which one of the following is more reactive towards SN2 reaction ?

  • (CH3)3CX

  • (CH3)2CHX

  • CH3CH2X

  • CH3X


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579.

The reaction between an alkyl halide and sodium metal in dry ether is called

  • Clemmensen reduction

  • Kolbe's reaction

  • Wurtz 's reaction

  • Cannizaro's reaction


C.

Wurtz 's reaction

When alkyl halides reacts with sodium metal in presence of dry ether to give higher alkane, the reaction is known as Wurtz's reaction.

CH3BrMethyl bromide + 2Na + BrCH3 Dry ether CH3CH3Ethane + 2NaBr


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580.

DDT is related to

  • insecticide

  • fungicide

  • chlorination

  • florination


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