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 Multiple Choice QuestionsMultiple Choice Questions

741.

CH3CH=CHCH3 + CHCl3 + t-BuOK ➔ A. A is


742.

In which of the following preparations of ether, the configuration about chiral centre is not retained?


743.

Which ofthe following compounds is not chiral?

  • 1-Chloropentane

  • 2-Chloropentane

  • 1-Chloro-2-methyl pentane

  • 3-Chloro-2-methyl pentane


744.

Which ofthe following molecules will not show optical activity?


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745.

Decreasing order of stability of ions is.
(i) CH3 - C+H - CH3

(ii) CH- C+H - OCH3

(iii) CH3 - C+H - COCH3

  • (i) > (ii) > (iii)

  • (ii) > (i) > (iii)

  • (ii) > (iii) > (i)

  • (iii) > (i) > (ii)


746.

Which of these compounds is synthesised by chloral?

  • DDT

  • BHC

  • Chloroform

  • Michlers ketone.


747.

What is B ?


748.

The function of AlCl3, in Friedel-Craft's reaction is to

  • absorb HCl

  • absorb water

  • produce nucleophile

  • produce electrophile.


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749.

Consider the reaction,

The correct explanation is

  • the product is formed due to nucleophilic substitution

  • the product is formed according to Saytzeff's rule

  • conjugated double bond product is formed, due to higher stability because of resonance stabilization

  • (CH3)3CO- is a better leaving group


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750.

Williamson's synthesis involves :

  • SN1 mechanism

  • nucleophilic addition

  • SN2 mechanism

  • SE  mechanism


C.

SN2 mechanism

Williamson's synthesis : A reaction in which sodium or potasium alkoxide is heated with an alkyl halide to give ether by the reaction sample as well as mixed ethers can be prepared .This is an example of nucleophilic substitution and follows SN2 mechanism .

RONa + XR  RORsimple + NaXether

RONa + XR'  R-O-R'mixed ether + NaX


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