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 Multiple Choice QuestionsShort Answer Type

141.

What happens when:

(i) Ethyl alcohol is heated in the presence of Al2O3 at 493 K? 

(ii) Ethylene dibromide is heated with zinc dust?

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 Multiple Choice QuestionsLong Answer Type

142.

Explain the mechanism of the following reaction:

straight C subscript 2 straight H subscript 5 OH space rightwards arrow from 440 space straight K to Conc. space straight H subscript 2 SO subscript 4 of space CH subscript 2 space equals space CH subscript 2 space plus space straight H subscript 2 straight O

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143.

How are alkenes prepared from Alkynes ?

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 Multiple Choice QuestionsShort Answer Type

144.

The straight pi-bond is weaker than carbon-carbon σ bond. Explain.

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145.

Why are alkenes more reactive than alkanes ?


Alkenes have a carbon-carbon double bond (>C = C<) in their molecules. The >C = C< bond is made up of one strong σ bond and one weak  bond. The electrons of the  bond are more exposed which increase reactivity. In other words, the presence of  bond (formed by the sideways overlapping of atomic orbital) makes alkenes highly reactive chemically as compared to alkanes. 

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 Multiple Choice QuestionsLong Answer Type

146.

Why do alkenes undergo electrophilic addition reactions?

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147.

Discuss the mechanism of addition of bromine to ethylene.

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148.

Discuss the mechanism of addition hydrogen acids to symmetrical alkenes. Justify the order of reactivity of halogen acids HI > HBr > HCl.

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149.

Define Markownikoff's rule giving an example.

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150. Give the mechanism of Markownikoffs rule as applied to unsaturated hydrocarbons.
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