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 Multiple Choice QuestionsMultiple Choice Questions

281.

Friedel-Craft's reaction using MeCl and anhydrous AlCl3 will take place most efficiently with

  • benzene

  • nitrobenzene

  • acetophenone

  • toluene


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282.

Under identical conditions, the SN1 reaction will occur most efficiently with

  • tert-butyl chloride

  • 1-chlorobutane

  • 2-methyl-1-chloropropane

  • 2-chlorobutane


A.

tert-butyl chloride

SN1  reaction is most effective in 3° carbon. (i)(CH3)3-C-Cltert-butyl chloride (3 °)             (ii) CH3CH2CH2Cl1-chlorobutane (1 °) (iii) Cl-CH2-CH(CH3)-CH32-methyl-1-chloropropane (1 °)(iv) CH3CH2CH(Cl)CH32-chlorobutane (2°) 


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283.

An equimolar mixture of toluene and chlorobenzene is treated with a mixture of conc.H2SO4 and cone. HNO3. Indicate the correct statement from the following.

  • p-nitrotoluene is formed in excess

  • equimolar amounts of p-nitrotoluene and p-nitrochlorobenzene are formed

  • p-nitrochlorobenzene is formed in excess

  • m-nitrochlorobenzene is formed in excess


284.

Among the following carbocations:
Ph2C+CH2Me (I), PhCH2CH2CH+Ph (II),Ph2CHCH+Me (III) and Ph2C(Me)CH2 (IV), the order of stability is

  • IV > II > I > III

  • I > II > III > IV

  • II > I > IV > III

  • I > IV > III > II


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285.

The major product obtained in the reaction

               


286.

The reaction of toluene with chlorine in presence of ferric chloride gives predominatly

  • benzoyl chloride

  • m - chlorotoluene

  • benzyl chloride

  • o- and p - chlorotoluene


287.

In benzene, the triple bond consists of

  • one sp-sp sigma bond and two p-p pi bonds

  • two sp-sp sigma bonds and one p-p pi bond

  • one sp2-sp2 sigma bond, one p-p pi bond

  • one sp2-sp2 sigma bond, one sp2-sp2 pi bond and one p-p pi bond


288.

A and B respectively are

  • Both 

  • Both 


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289.

Which of the following compounds cannot be prepared singly by the Wurtz reaction?

  • C2H6

  • (CH3)2CHCH3

  • CH3CH2CH2CH3

  • All of the above can be prepared


290.

The product Y is

  • p-chloro nitrobenzene

  • o-chloro nitrobenzene

  • m-chloro nitrobenzene

  • o, p-dichloro nitrobenzene


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