When but-2-yne is treated with Na in liquid ammonia from Chemist

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 Multiple Choice QuestionsMultiple Choice Questions

321.

The reaction in propene with HBr is presence of peroxide proceeds through the intermediate

  • H3C - C.H - CH3

  • H3C - C.H -CH2Br

  • H3C - CH|Br - C.H2

  • H3C - CH2C.H2


322.

The total number of monohalogenated products formed by halogenation of 2, 4, 4-trimethylhexane are,

  • 5

  • 7

  • 6

  • 8


323.

If 27 g of water is formed during complete combustion of pure propene (C3H6), the mass of propene burnt is

  • 42 gm

  • 21 gm

  • 14 gm

  • 56 gm


324.

When methane is heated with dioxygen in the presence of Mo2O3 catalyst, the organic product obtained is

  • methanal

  • ethanoic acid

  • methanol

  • ethanol


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325.

The products obtained by the ozonolysis of 2-ethylbut-1-ene are

  • propanone and ethanal

  • methanal and 3-pentanone

  • ethanal and 3-pentanone

  • butanal and ethanal


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326.

When but-2-yne is treated with Na in liquid ammonia

  • cis-2-butene is obtained

  • trans-2-butene is formed

  • n-butane is the major product

  • it rearranges to but-1-yne


B.

trans-2-butene is formed

When but-2-yne is treated with Na in liquid ammonia, addition of two H-atoms takes place at the triple bonded carbon atoms in trans manner and results in the formation of trans-2-butene.


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327.

When n-hexane is heated with anhydrous AlCl3 and HCl gas, the major product obtained is

  • 1-chlorohexane

  • 2-chlorohexane

  • 3-chlorohexane

  • mixture of 2-methylpentane and 3-methylpentane


328.

The decreasing order of acidic character among ethane (I), ethene (II), ethyne (III) and propyne (IV) is

  • (I) > (II) > (III) > (IV)

  • (II) > (III) > (I) > (IV)

  • (III) > (IV) > (II) > (I)

  • (IV) > (III) > (II) > (I)


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329.

The alkene that will give the same product with HBr in the absence as well as in the presence of peroxide is

  • 2-butene

  • 1-butene

  • propene

  • 2-methylpropene


330.

Chlorination of benzene in the presence of halogen carrier is an example of

  • aromatic nucleophilic substitution

  • aromatic electrophilic substitution

  • aromatic nucleophilic addition

  • aromatic electrophilic addition


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