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 Multiple Choice QuestionsMultiple Choice Questions

331.

Two organic compounds X and Y on analysis gave the same percentage composition namely; C = (12/13) × 100% and H = (1/13) × 100%. However, compound X decolourises bromine water while compound Y does not. The two compounds X and Y may be respectively 

  • acetylene and ethylene

  • acetylene and benzene

  • ethylene and benzene

  • toluene and benzene


332.

For preparing an alkane, a saturated solution of sodium or potassium salt of a carboxylic acid is subjected to

  • hydrolysis

  • electrolysis

  • oxidation

  • hydrogenation


333.

The reaction of  with HBr gives predominantly


334.

An organic compound with molecular formula C6H12 upon ozonolysis give only acetone as the product. The compound is

  • 2,3-dimethyl-1-butene

  • 3-hexane

  • 2-hexene

  • 2,3-dimethyl-2-butene


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335.

Which one of the following carbanions is the least stable?

  • CH3CH2-

  • CH3-

  • (CH3)3C-

  • HC≡C-


336.

An aromatic hydrocarbon with empirical formula C5H4 on treatment with concentrated H2SO4 gave a monosulphonic acid. 0.104 g of the acid required 10 mL of N20 NaOH for complete neutralisation. The molecular formula of hydrocarbon is 

  • C5H4

  • C10H8

  • C15H12

  • C20H16


337.

An alkene having the molecular formula C9H18 on ozonolysis gives 2, 2-dimethyl propanal and 2-butanone. The alkene is :

  • 2, 2, 2-trimethyl-3-hexene

  • 2, 2, 6-trimethyl-3-hexane

  • 2, 3, 4-trimethyl-2-hexene

  • 2, 2, 4-trimethyl-3-hexene


338.

Observe the following reactions and predict the nature of A and B:

  • A and B both are 

  • A and B both are 

  • A is  and B is 

  • A is  and B is 


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339.

Nitration of aniline in strongly acidic medium, result in the formation of m-nitroaniline also. This is because :

  • amino group is meta orienting during electrophilic substitution reaction

  • nitro group goes always to the meta position irrespective of the substituents

  • nitration of aniline is a nucleophilic substitution reaction in strongly acidic medium

  • in strongly acidic conditions aniline is present as anilinium ion


B.

nitro group goes always to the meta position irrespective of the substituents

Nitro group goes always to meta position, in aromatic compounds, irrespective to the substituents.


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340.

How many σ and Π bonds are present in toluene?

  • 3Π + 8σ

  • 3Π + 10σ

  • 3Π + 15σ

  • 6Π + 3σ


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