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 Multiple Choice QuestionsMultiple Choice Questions

401.

Which one of the following hydrocarbons has octane number 100?

  • 2, 2, 3-trimethylpentane

  • 2, 3, 3-trimethylpentane

  • 2, 2, 4-trimethylpentane

  • 2, 3, 4-trimethylpentane


402.

Which one of the following is the best reagent to accomplish the following conversion ?

CH3CH2Br ? CH3-CH3

  • NaBH3

  • Na|ether

  • Zn|C2H5OH

  • Mg followed by H3O+


403.

Benzene has the following hybridisation

  • sp

  • sp2

  • sp3

  • dsp2


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404.

Propyne and propene can be distinguished by

  • conc. H2SO4

  • Br2 in CCl4

  • dil. H2SO4

  • AgNO3 in ammonia


D.

AgNO3 in ammonia

Propyne because of the presence of acidic H-atom, reacts with ammoniacal AgNO3 and gives grey/ white silver propynilide. Propene, on the other hand, does not have any acidic H-atom, so it does not react with ammoniacal AgNO3. Hence, these two are separated by this reagent.

CH3C ≡ CH + AgNO3 + NH4OH → CH3C ≡ CAg ↓ + NH4NO3 + H2O

CH3CH ≡ CH2 + AgNO3 + NH4OH → No reaction


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405.

C2H5Cl CuILi C2H5Cl n-butane. This method is

  • Wurtz synthesis

  • Kolbe synthesis

  • Corey House synthesis

  • Friedel-Craft synthesis


406.

One of the isomer of the 5th member of alkyne series is optically active. It is

  • 4-methyl pent-2-yne

  • 3-methyl pent-1-yne

  • 4-methyl pent-1-yne

  • 3, 3-dimethyl but-1-yne


407.

Which compound present in diesel?

  • Cetane

  • TiCl4

  • Cyclo pentandenyl manganese carbonyl

  • Iso octane


408.

Acetylene and HCHO react in presence of copper acetylide catalyst to form

  • But-2-yne-1, 2-diol

  • But-1-yne-1, 4-diol

  • But-2-ene-1, 4-diol

  • 2-butyne-1, 4-diol


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409.

Which of the following substance is not related with HVZ reaction?

  • α-bromo acetic acid

  • Zn/ Hg

  • Cl2

  • Red P


410.

Which of the following compound show acidic nature?

  • but-1-yne

  • but-2-yne

  • but-1-ene

  • buta-1, 3-diene


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