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 Multiple Choice QuestionsMultiple Choice Questions

481.

In the following reaction, number of possible structure is

  • 1

  • 2

  • 5

  • 6


482.

In Zeigler Natta polymerisation of ethylene, the active species is

  • AlCl3

  • Et3Al

  • CH2CH2

  • Ti3+


483.

The number of possible alkynes with molecular formula C5H8 is

  • 1

  • 3

  • 5

  • 8


484.

How many delocalised π-electrons are there in the following compound?

  

  • 1

  • 2

  • 3

  • 6


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485.

Which of the following is an anti-knocking compound?

  • TEL

  • LTC

  • Freon

  • Gasoline


486.

The cumulated alkadiene is


487.

The IUPAC name of 

   is

  • 4-bromo-2-chloro-5-iodo-1-fluorobenzene

  • 2-carbamoylhex-3-enal

  • 1-bromo-2-chloro-3-fluoro-6-iodobenzene

  • 2-bromo-1-chloro-5-fluoro-3-iodobenzene


488.

Compound  which of the following prefix?

  • trans

  • Anti

  • E

  • Z


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489.

Friedel-Crafts reaction is not related with

  • acylation

  • reduction

  • sulphonation

  • nitration


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490.

Assertion (A): Reaction of 1-butene with HBr gives 1-bromobutane as major product.

Reason (R): Addition of hydrogen halides to alkenes proceeds according to Markownikoffs rule.

The correct answer is

  • A and R are correct and R is the correct explanation of A

  • A and R are correct but R is not the correct explanation of A.

  • A is correct but R is not correct

  • A is not correct but R is correct


D.

A is not correct but R is correct

According to Markownikoff's rule, the addition of reagents such as HX, H2O and HOX with unsymmetrical alkanes occurs in such a way that the negative part of the adding molecule goes to that carbon atom of the double bond which carries lesser number of hydrogen atoms.

 CH3CH2CH=CH2 + HBrAbsence of peroxidesDark CH3CH2-CHBr-CH32-bromobutane (major product) + CH3CH3-CH2-CH2-Br1- bromobutane ( minor product)


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