In the eclipsed conformation of ethane, the dihedral angle betwee

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 Multiple Choice QuestionsMultiple Choice Questions

531.

What is the product P ?

  • Both (a) and (b)


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532.

In the eclipsed conformation of ethane, the dihedral angle between the hydrogen atoms of adjacent methyl groups is :

  • 60°

  • 120°

  • 180°


C.

In the eclipsed conformation of ethane, each of the hydrogen atom on the back carbon lies exactly behind each of the hydrogen atoms on the front carbon and the dihedral angle between the two is 0°.


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533.

The major product of the addition of water molecule to propyne in the presence of mercuric sulphate and dilute sulphuric acid is :

  • ethanal

  • 2-propanol

  • propane

  • propanone


534.

Which of the following statements is not an essential feature of an optically active molecule ?

  • It will rotate the plane of polarised light

  • It will have a non-superimposable mirror image

  • It will have no element of symmetry

  • It will have an asymmetric carbon atom


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535.

The reagent which could distinguish between 1-hexyne and 1-hexene is :

  • Ag(NH3)2+

  • KMnO4

  • Br2 in CCl4

  • H2SO4


536.

Choose the correct reagent required to carry out the transformation :

  • Zn + conc. HCl

  • conc. H2SO4

  • Li then H2O

  • H2/Pt


537.

The heat liberated when 1.89 g of benzoic acid is burnt in a bomb calorimeter at 25°C and it increases the temperature of 18.94 kg of water by 0.632°C. If the specific heat of water at 25°C is 0.998 cal/g-deg, the value of the heat of combustion of benzoic acid is

  • 881.1 kcal

  • 771.2 kcal

  • 981.1 kcal

  • 871.2 kcal


538.

Which of the following alkenes will give same product by any method out of hydration, hydroboration-oxidation and oxymercuration-demercuration? 

  • CH3CH=CH2

  • CH3CH=CHCH3

  • CH3CH(CH3)CH=CH2


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539.

The compound formed by the ozonolysis of acetylene :

  • glycol

  • acetic acid

  • ethylene ozonide

  • glyoxal


540.

The compound which have conjugate double bond :

  • butyne

  • butylene

  • isobutylene

  • butadiene


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