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 Multiple Choice QuestionsMultiple Choice Questions

581.

Assertion : Addition of HBr on 2-butene gives two isomeric products.

Reason: Addition of HBr on 2-butene follows Markovnikov's rule.

  • If both assertion and reason are true and reason is the correct explanation of the assertion.

  • If both assertion and reason are true but reason is not the correct explanation of the assertion.

  • If assertion is true, but reason is false.

  • Both assertion and reason are false statements.


582.

Assertion : p-O2N- C6H5COCH3 is prepared by Friedel Crafts acylation of nitrobenzcne.

Reason : Nitrobenzene easily undergoes electrophilic substitution reaction.

  • If both assertion and reason are true and reason is the correct explanation of assertion.

  • If both assertion and reason are true but reason is not the correct explanation of assertion.

  • If assertion is true but reason is false.

  • If both assertion and reason are false.


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583.

Assertion : Alkyl isocyanides in acidified water give alkyl formamides.

Reason : In isocyanides, carbon first acts as a nucleophile and then as an electrophile.

  • If both assertion and reason are true and reason is the correct explanation of assertion.

  • If both assertion and reason are true but reason is not the correct explanation of assertion.

  • If assertion is true but reason is false.

  • If both assertion and reason are false.


A.

If both assertion and reason are true and reason is the correct explanation of assertion.

In an isocyanide, first an electrophile and then a nucleophile add at the carbon to form a species which usually undergoes further transformation.

RN+  C + E+  RN+  CE Nu RN = C(Nu)ERN + C + H2O  RN = CHOH RNHCHOalkyl formamide


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584.

Assertion : Cyclopentadienyl anion is much more stable than allyl anion.

Reason : Cyclopentadienyl anion is aromatic in character.

  • If both assertion and reason are true and reason is the correct explanation of assertion.

  • If both assertion and reason are true but reason is not the correct explanation of assertion.

  • If assertion is true but reason is false.

  • If both assertion and reason are false.


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585.

Action of acetylene on dilute H2SO4 gives :

  • acetic acid

  • acetaldehyde

  • acetone

  • acetoacetic ester


586.

The treatment of benzene with isobutene in the presence of sulphuric acid gives

  • iso -butyl benzene

  • tert -butyl benzene

  • n -butyl benzene

  • no reaction


587.

The strongest base among the following is


588.

The length of C - C bond in benzene is :

  • 1.22 Ao

  • 1.54 Ao

  • 1.39 Ao

  • 1.56 Ao


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589.

Which of the following is most stable ?

  • 1-butene

  • 1-pentene

  • 2-butene

  • 2-pentene


590.

The compound having only primary hydrogen atoms is

  • isobutene

  • 2,3-dimethylbutene

  • cyclohexane

  • propyne


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