Assertion : The pKa of acetic acid is lower than that of phenol.R

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 Multiple Choice QuestionsMultiple Choice Questions

591.

Among the following the aromatic compound is


592.

Assertion : Styrene on reaction with HBr gives 2-bromo-2-phenyl ethane.

Reason: Benzyl radical is more stable than alkyl radical.

  • If both assertion and reason are true and reason is the correct explanation of assertion

  • If both assertion and reason are true but reason is not the correct explanation of assertion

  • If resason is true but assertion is false

  • If both assertion and reason are false.


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593.

Assertion : The pKa of acetic acid is lower than that of phenol.

Reason : Phenoxide ion is more resonance stabilised

  • If both assertion and reason are true and reason is the correct explanation of assertion

  • If both assertion and reason are true but reason is not the correct explanation of assertion

  • If assertion is true but reason is false

  • If both assertion and reason are false.


C.

If assertion is true but reason is false

Lower the value of pKa, more acidic will be the compound. Acetic acid is more acidic than phenol. This indicates that carboxylate ion should be more stable than the phenoxide ion and it is clear that carboxylate ion has more equivalent resonating structures than the phenoxide ion.


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594.

Which of the following is aromatic?


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595.

Which ofthe following is most stable carbocation?

  • CH3+

  • CH3CH2C+H2

  • CH3C+HCH3

  • CH3-(CH3)C+-CH3


596.

Assertion : Alkyl benzene is not prepared by Friedel-Crafts alkylation of benzene.

Reason : Alkyl halides are less reactive than acyl halides.

  • If both assertion and reason are true and the reason is the correct explanation of the assertion.

  • If both assertion and reason are true and the reason is not the correct explanation of the assertion.

  • If assertion is true but reason is false.

  • If both assertion and reason are false.


597.

Rate determining step in nitration of benzene is

  • formation of NO2+

  • formation of carbocation

  • replacement of H atom

  • none of these.


598.

1,4-dimethylbenzene on heating with anhydrous AlCl3 and HCl produces

  • 1, 2-dimethylbenzene

  • 1, 3-dimethylbenzene

  • 1, 2, 3-trimethylbenzene

  • ethylbenzene


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599.

In 2-butene, which one of the following statements is true?

  • C1-C2 bond is sp3-sp3 -σ-bond

  • C2-C3 bond is sp3-sp2 -σ-bond

  • C1-C2 bond is an sp3-sp2 -σ-bond

  • C1-C2 bond is an sp2-sp2 -σ-bond


600.

The stability of Me2C=CH2 is more than that of MeCH2CH=CH2 due to:

  • inductive effect of the Me groups

  • resonance effect of the Me groups

  • hyperconjugation effect of the Me groups

  • resonance as well as the inductive effect of the Me groups


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