What do you understand by:
(i) electron deficient
(ii) electron-precise and
(iii) electron rich compounds of hydrogen?
Provide justification with suitable examples.
What characteristics do you expect from an electron-deficient hydride with respect to its structure and chemical reactivity ?
What do you understand by the term ‘non-stoichiometic hydrides’? Do you expect this type of hydrides to be formed by alkali metals?
Saline hydrides are known to react with water violently producing fire. Can CO2, a well-known fire extinguisher, be used in this case? Explain.
What do you expect the nature of hydrides if formed by elements of atomic numbers 15, 19, 23, 44 with dry dihydrogen? Compare their behaviour towards water.
Can Phosphorus with outer electronic configuration 3s23p3 form PH5?
Or
P forms PH3 but not PH5. Comment.
Electrical conductance. The order of increasing electrical conductance is
BeH2 < CaH2 < TiH2.
Reason: BeH2 being a covalent hydride, therefore it does not conduct electricity. On the other hand, CaH2 conducts electricity in the fused state and TiH2 conducts electricity at room temperature. Hence order of increasing electrical conductance is
BeH2<CaH2<TiH2