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 Multiple Choice QuestionsLong Answer Type

11. Calculate the mass of ascorbic acid (Vitamin C, C6H8O6) to be dissolved in 75 g of acetic acid to lower its melting point by 1.5 0C. Kf= 3.9 k kg mol–1.
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12. Calculate the osmotic pressure in pascals exerted by a solution prepared by dissolving 1.0 g of polymer of molar mass 185,000 in 450 mL at 370C.
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 Multiple Choice QuestionsShort Answer Type

13. Suppose a solid solution is formed between two substances, one whose particles are very large and the other whose particles are very small. What kind of solid solution is this likely to be?
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14. Amongst the following compunds identify which are insoluble, partially soluble and highly soluble in water?
(i) phenol (ii) toluene (iii) formic acid (iv) ethylene glycol (v) chloroform, (vi) pentanol.
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15. Two liquids A and B boils at 1450C and 1900C respectively. Which of them has a higher vapour pressure at 800C ?
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16. Define ‘mole fraction’ of a substance in a solution.


Mole fraction: Commonly used symbol for mole fraction is x and subscript used on the right hand side of x denotes the component.
It is defined as:
Mole fraction of a component =

Number of moles of the component Total number of moles of all the components


For example, in a binary mixture, if the number of moles of A and B are nA and nB respectively, the mole fraction of A will be
 
x =nAnA + nB

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17. What is expected value of Van’t Hoff factor for K3 [Fe(CN)6] in dilute solution?
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18. State the formula relating pressure of a gas with its mole fraction in a liquid solution in contact with it.
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19. What would be the value of Van’t Hoff factor for a dilute solution of K2SO4 in water?
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20. In the determination of molar mass of A+B using a colligative property, what may be the value of Van’t Hoff factor if the solute is 50% dissociated?
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