The freezing point of water is depressed by 0.37°C in a 0.01 molal NaCl solution. The freezing point of 0.02 molal solution of urea is depressed by
0.37°C
0.74°C
0.185°C
0°C
A.
0.37°C
We know,
tf = i kjm
where, tf = depression in freezing point; i = van't Hoff factor; m = molality and kf = freezing point depression constant.
For 0.01 molal NaCl solution
0.37 = 2 × kf × 0.01
kf = ...(i)
For 0.02 molal urea solution
tf = 1 × kf × 0.02
tf = ...(ii)
Blood cells will remain as such in:
hypertonic solution
hypotonic solution
isotonic solution
none of the above
The mixture that forms maximum boiling azeotrope is:
Ethanol + Water
Acetone + Carbon disulphide
Heptane + Octane
Water + Nitric acid
For an ideal solution, the correct option is :
Δmix V ≠ 0 at constant T and P
Δmix H = 0 at constant T and P
Δmix G = 0 at constant T and P
Δmix S = 0 at constant T and P