Among the elements from atomic number 1 to 36, the number of elements which have an unpaired electron in their s subshell is
2
7
6
9
Consider the following sets of quantum numbers. Which of the following setting is not permissible arrangement of electrons in an atom?
n = 4; l = 0; m = 0; s =
n = 5; l = 3; m = 0; s =
n = 3; l = 2; m = -2; s =
n = 3; l = 2; m = -3; s =
What is the effect of increasing pressure on the dissociation of PCl5 according to the equation?
PCl5 (g) PCl3 (g) + Cl2 (g)
Dissociation decreases
Dissociation increases
Dissociation does not change
None of the above
A.
Dissociation decreases
According to Le-Chatelier principle the reactions in which member of moles are increasing in forward reaction are favoured at low pressure or high volume.
PCl5 (g) PCl3 (g) + Cl2 (g)
Since, number of moles are increasing in the forward reaction in above reaction.
Reaction is favoured at low pressure. At high pressure, rate of dissociation of PCl5 decreases.
The ground state term symbol for an electronic state is governed by :
Heisenberg's principle
Hund's rule
Aufbau principle
Pauli exclusion principle
The correct set of quantum number for the unpaired electrons of chlorine atoms is
2, 1, -1, +1/2
2, 0, 0,+ 1/2
3, 1, 1, ±1/2
3, 0, 0, ±1/2