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361.

A crystalline solid X reacts with dil. HCl to liberate a gas Y. Y decolourises acidified KMnO4. When a gas 'Z' is slowly passed into an aqueous solution of Y, colloidal sulphur is obtained X and Z could be respectively

  • Na2S, SO3

  • Na2SO4, H2S

  • Na2SO3, H2S

  • Na2SO4, SO2


C.

Na2SO3, H2S

Na2SO3 (X) reacts with dil. HCl to liberate SO2 gas (Y) Thus SO2 gas decolourises acidified KMnO4. On passing H2S gas (Z) into aqueous solution of SO2 (i.e.,H2SO3), colloidal sulphur is obtained. Complete reactions are as follows-

Na2SO3X + 2HCl → 2NaCl + H2O + SO2Y

2KMnO4Purple + 2H2O + 5SO2Y → K2SO42MnSO4Colourless + 2H2SO4

H2O + SO2 Y H2SO4Aqueous solution of Y

H2SO32H2SZ  2S + 3H2OColloidal sulphur


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362.

Gold sol is not

  • a macromolecular colloid

  • a lyophobic colloid

  • a multimolecular colloid

  • negatively charged colloid


363.

For Freundlich isotherm a graph of log x/m is plotted against log p. The slope of the line and its y-axis intercept, respectively corresponds to

  • 1n , k

  • log 1n , k

  • 1n , log k

  • log 1n, log k


364.

The electrolyte having maximum flocculation value for AgI/Ag+ sol is

  • NaCl

  • Na2S

  • Na2SO4

  • Na3PO4


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365.

Which of the following curve is in accordance with Freundlich adsorption isotherm?


366.

Which of the following statements is incorrect with respect to physisorption?

  • The forces involved are van der Waals' forces

  • More easily liquefiable gases are adsorbed easily

  • Under high pressure it results into multimolecular layer on adsorbent surface

  • Hadsorption is low and positive


367.

Sulphur sol contains

  • discrete S-atoms

  • discrete S molecules

  • large aggregates of S molecules

  • water dispersed in solid sulphur


368.

Which of the following colloids cannot be easily coagulated?

  • Lyophobic colloids

  • Multimolecular colloids

  • Macromolecular colloids

  • Irreversible colloids


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369.

The pressure of real gases is less than that of ideal gas because of

  • increases in the kinetic energy of the molecules

  • increases in the number of collisions

  • intermolecular attraction

  • finite size of particles


370.

An aerosol is a:

  • dispersion of a solid or liquid in a gas

  • dispersion of a solid in a liquid

  • dispersion of a liquid in a liquid

  • solid solution


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