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The Solid State

Short Answer Type

41. Define non-stiochiometry defect in crystals?

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42. What is the arrangement of Zn²⁺ and S^2– ions in Zinc blende (ZnS) crystal structure?

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43. explain the effect of Frenkel structural defect on the electrical conductance of a crystalline solid?

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44. An ionic compound AB₂ possess CaF₂type crystal structure. What the co-ordination number of A²⁺ and B^– ions in crystal of AB₂ explain.

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45. What kind point defect lowers the density of a crystal?

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46. What do you mean by ‘point defects' in crystals?

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47. Define dislocation in crystals.

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48. Explain the term ‘dislocations’ in relation to crystals?

Crystal defect. Line defects, or dislocations, are lines along which whole rows of atoms in a solid are arranged anomalously. The resulting irregularity in spacing is most severe along a line called the line of dislocation. Line defects can weaken or strengthen solids.

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49. Why does zinc oxide exhibit enhanced electrical conductivity on heating?

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50. In a body centred unit cell, one of the diagonals contains two extra atoms. Find the number of atoms present per unit cell?

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