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The d-And-f-Block Elements

Short Answer Type

81. Zn and Hg has little tendency to form complex compounds. Why?

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82. What is the oxidation state of chromium in (a) potassium dichromate, (b) potassium chromate?

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83.

Give chemical equation of reaction when pyrolusite ore is fused with KOH in presence of air.

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84.

Why is hydrochloric acid not used to acidify a permanganate solution in volumetric estimation of Fe²⁺ or C₂O₄^2–?

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85.

Write an ionic equation representing the oxidising property of acidified potassium permanganate solution.

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86. Give one reaction in which neutral solution of KMnO₄ acts as an oxidizing agent.

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87. How would you convert potassium dichromate to potassium chromate?

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88. What happens when SO₂ gas is passed through an acidified K₂Cr₂O₇ solution?

Sulfur dioxide gas turns acidified potassium dichromate solution from orange to green reduced chromium +4 to +3.

K₂Cr₂O₇ + 2H₂SO₄+ 3SO₂ → 2Cr₂(SO₄)₃ + K₂SO₄+ H₂O

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89. Why is K₂Cr₂O₇ generally preferred over Na₂Cr₂O₇ in volumetric analysis although both are oxidising agents?

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90. Write a balanced equation for the reaction of K₂Cr₂O₇ with ferrous sulphate solution in presence of dil. H₂SO₄.

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Short Answer Type

88. What happens when SO2 gas is passed through an acidified K2Cr2O7 solution?

88. What happens when SO₂ gas is passed through an acidified K₂Cr₂O₇ solution?