170. Compare the general characteristics of the first series of the transition metals with those of the second and third series metals in the respective vertical columns. Give special emphasis on the following points:
(i) electronic configuration (ii) oxidation states (iii) ionisation enthalpies and (iv) atomic sizes.

(ii) Oxidation states:

(iii) Ionization enthalpies

In each of the three transition series, the first ionisation enthalpy increases from left to right. However, there are some exceptions. The first ionisation enthalpies of the third transition series are higher than those of the first and second transition series. This occurs due to the poor shielding effect of 4felectrons in the third transition series.

Certain elements in the second transition series have higher first ionisation enthalpies than elements corresponding to the same vertical column in the first transition series. There are also elements in the 2ndtransition series whose first ionisation enthalpies are lower than those of the elements corresponding to the same vertical column in the 1sttransition series.

(iv) Atomic Sizes

Atomic size generally decreases from left to right across a period. Now, among the three transition series, atomic sizes of the elements in the second transition series are greater than those of the elements corresponding to the same vertical column in the first transition series. However, the atomic sizes of the elements in the third transition series are virtually the same as those of the corresponding members in the second transition series. This is due to lanthanoid contraction.