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 Multiple Choice QuestionsShort Answer Type

181.

Explain the following facts:
Transition metals form coloured complexes.

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182.

Give reasons:
Among transition metals, the highest oxidation state is exhibited in oxoanions of a metal.

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183.

Give reasons:
Ce4+ is used as an oxidising agent in volumetric analysis.

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184.

Give reasons:
Zn2+ salts are white while Cu2+ salts are blue.

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185.

Why La, Gd and Lu has low value of 3rd ionisation enthalpies?

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186. Why is cerium a good analytical reagent?
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187. Given below are the electrode potential values, E° for some of the first row of transition elements:
Elements V(23) Cr(24) Mn(25)Fe(26)Co(27)Ni(28) Cu(29)
M2+/M(V) –1.18 – 0.91 – 0.44 – 0.28 –0.28 –0.25 +0.34
Explain the irregularities in these values on the basis of electronic structures of atoms.
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188.

Complete the following reaction equations:
(i) Cr2O7 2 + Sn2+ + H+ →
(ii) MnO4– + Fe2+ + H+ →

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189.

Actinide cations are coloured? Why?

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190. Eu2+, Yb2+ are good reductants whereas Tb+4 is an oxidant. Why?


The electronic configuration of Eurponium is 4f7 6s2 and Ytterbium is 4f14 6s2. Eu and Yb in +2 oxidation states acquires half filled (4f7) and fully filled (4f 14) configuration but still they oxidises to their common +3 state and thus acts as strong reducing agents or reductants.
Tb in +4 state has 4f7 half filled stable configuration but it readily gets reduced to common +3 state and hence acts as oxidant.
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