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 Multiple Choice QuestionsShort Answer Type

191.

Why Am and Cm have exceptional configuration in actinoids?

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 Multiple Choice QuestionsLong Answer Type

192. Write the main differences in lanthanides and actinides.
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 Multiple Choice QuestionsShort Answer Type

193. Why the actinoids show more variable oxidation states than lanthanoids?
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194. What is actinoid contraction? How is it different from lanthanoid contraction?


The decrease in the atomic as well as ionic sizes of actinoids along the series is called actinoid contraction. The actinoid in +3 oxidation state shows regular decrease in their atomic size.
It is different from the lanthanoid contraction.

As we move along the lanthanoid series, the atomic number increases gradually by one. This means that the number of electrons and protons present in an atom also increases by one. As electrons are being added to the same shell, the effective nuclear charge increases. This happens because the increase in nuclear attraction due to the addition of proton is more pronounced than the increase in the interelectronic repulsions due to the  addition of electron. Also, with the increase in atomic number, the number of electrons in the 4f orbital also increases. The 4f electrons have poor shielding effect. Therefore, the effective nuclear charge experienced by the outer electrons increases. Consequently, the attraction of the nucleus for the outermost electrons increases. This results in a steady decrease in the size of lanthanoids with the increase in the atomic number. This is termed as lanthanoid contraction.

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195. Why are Ni2+ compounds thermodynamically more stable than Pt2+ compounds while Pt4+ compounds are relatively more stable than Ni4+ compounds?
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196. Compare the magnetic behaviour of actinoids with lanthanoids.
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197.

Compare the chemical reactivity of actinoids with lanthanoids.

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198.

Account for the following facts:
The reduction of a metal oxide is easier if the metal formed is in liquid state at the temperature of reduction.

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199.

Account for the following facts:
The reduction of Cr2O3 with Al is the thermo-dynamically feasible, yet it does not occur at room temperature.

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200.

Account for the following facts:
Pine oil is used in froth floatation process.

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