Which of the following complex has zero magnetic moment (spin only)?
[Ni(NH3)6]Cl2
Na3[FeF6]
[Cr(H2O)6]SO4
K4[Fe(CN)6]
Among the following the compound that is both paramagnetic and coloured is :
K2Cr2O7
(NH4)2(TiCl6)
VOSO4
K3[Cu(CN)4]
Which of the following is diamagnetic in nature ?
[Fe(CN)6]3-
[Ni(CO)4]
[MnCl4]2-
C.
[Ni(CO)4]
Diamagnetic substances have all paired electron
(a) [Fe(CN)6]3- oxidation state of Fe = +3
It has one unpaired electron and is paramagnetic.
(b) [NiCl4]2- Oxidation state of Ni= +2
It has two unpaired electrons and is paramagnetic.
(c) Ni(CO)4 Oxidation state of Ni=0
It has no unpaired electron and is diamagnetic.
(d) [MnCl4]2- Oxidation state of Mn= + 2
1t is paramagnetic as it has five unpaired electrons.
The point of dissimilarity between lanthanides and actinides is
three outermost shells are partially filled
they show oxidation state of + 3 (common)
they are called inner transition elements
they are radioactive in nature
The general electronic configuration of the transition elements is
(n-1)d10, (n+1)s2
(n- 1)d1-10, (n + 1)s1-2
(n- 1)d1-10, np6,ns2
(n- 1)d1-10, ns1-2