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 Multiple Choice QuestionsMultiple Choice Questions

431.

Most common oxidation states shown by cerium are

  • +2, +4

  • +3, +4

  • +3, +5

  • +2, +3


432.

Which gives + 7 oxidation state ?

  • Mn(25)

  • Cr (24)

  • Cu(29)

  • Fe(26)


433.

Which of the following transitions involves maximum amount of energy?

  • M-(g)M(g)

  • M(g) M(g)+

  • M(g)+  M(g)2+

  • M(g)2+ M(g)3+


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434.

Select the coloured compound amongst the following .

(At. no. Ti= 22, Cr= 24, Cu= 29, Zn= 30)

  • TiCl4

  • CrCl3

  • ZnCl3

  • CuCl


B.

CrCl3

22Ti = [Ar] 3d2 4s2        Ti4+ = [Ar]
(No unpaired electron)

 34Cr = [Ar] 3d5 4s1   Cr3+= (Ar] 3d3

 

(Three unpaired electrons)

30Zn =[Ar] 3d10 4s2     Zn = [An] 3d10

(All electrons paired)

29Zn =[Ar] 3d10 4s2     Zn+ = [An] 3d10

(All electrons paired)

Since, Cr3+ ion has 3 unpaired electrons, therefore its salt, i.e., CrCl3 will be coloured.


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435.

The only radioactive element among the lanthanoids is

  • gadolinium

  • holmium

  • promethium

  • neodymium


436.

Identify a 'chemical twin' among the following.

  • Zr-Ta

  • Nb-Tc

  • Hf-Re

  • Nb-Ta


437.

What is the general molecular formula of the product obtained on heating lanthaniods (Ln) with sulphur?

  • LnS

  • LnS3

  • Ln3S2

  • Ln2S3


438.

Choose the correct matching of transition metal ion and magnetic moment from the codes given below. (Atomic number: Ti = 22, V =23, Fe= 26)

Transition element Magnetic moment (BM)
A. Titanium (III) i. 4.9
B. Vanadium (II) ii. 1.73
C. Iron (II) iii. 3.87

  • A - ii; B - iii; C - i

  • A - ii; B - i; C - iii

  • A - i; B - ii; C - iii

  • A - i; B - iii; C - ii


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439.

The hardest lanthanide element is

  • Sm

  • La

  • Gd

  • Dy


440.

How is sodium chromate converted into sodium dichromate in the manufacture of potassium dichromate from chromite ore?

  • By the action of concentrated sulphuric acid

  • By roasting with soda ash

  • By the action of sodium hydroxide

  • By the action of limestone


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