What is the general outer electronic configuration of the coinage metals ?
ns2 np6
(n-1)d10 ns1
(n-1)d10 ns2
(n-1)d9 ns2
Assertion : for Mn3+/Mn2+ is more positive than Cr3+/Cr3+
Reason : The third ionization energy of Mn is larger than that of Cr.
If both assertion and reason are true and reason is the correct explanation of the assertion.
If both assertion and reason are true but reason is not the correct explanation of the assertion.
If assertion is true, but reason is false.
Both assertion and reason are false statements.
B.
If both assertion and reason are true but reason is not the correct explanation of the assertion.
It is known that the value of becomes more negative clown the series. As the chromium is present below in electrochemical series than Mn, so Mn has more positive value than Cr.
Mn 3d5 4s2, Mn 3d5 4
Cr 3d5 4s1 Cr 3d4 4
For elimination or one electron from Mn2+, more energy is required due to its stable configuration. That is why third ionization energy of Mn is larger than Cr.
Assertion : K2Cr2O7 is used as primary standard in volumetric analysis.
Reason : It has a good solubility in water.
If both assertion and reason are true and reason is the correct explanation of the assertion.
If both assertion and reason are true but reason is not the correct explanation of the assertion.
If assertion is true, but reason is false.
Both assertion and reason are false statements.
Assertion : Change in colour of acidic solution of potassium dichromate by breath is used to test drunk driver.
Reason : Change in colour is due to the complexation of alcohol with potassium di chromate.
If both assertion and reason are true and reason is the correct explanation of the assertion.
If both assertion and reason are true but reason is not the correct explanation of the assertion.
If assertion is true, but reason is false.
Both assertion and reason are false statements.
Assertion : SiF62- is known but SiCl62- is not.
Reason : Size of fluorine is small and its lone pair of electrons interacts with d-orbitals of Si strongly.
If both assertion and reason are true and reason is the correct explanation of assertion.
If both assertion and reason are true but reason is not the correct explanation of assertion.
If assertion is true but reason is false.
If both assertion and reason are false.
The general electronic configuration of transition elements, is :
(n-1)d1-5 ns0
(n-1)d1-10 ns1
(n-1)d1-10 ns2
(n-1)d1-10 ns1-2