Cupric compounds are more stable than their cuprous counterparts

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 Multiple Choice QuestionsMultiple Choice Questions

691.

Which of the following does not give oxygen on heating?

  • KClO3

  • Zn(ClO3)2

  • K2Cr2O7

  • (NH4)2Cr2O7


692.

Which ofthe following lanthanoid ions is diamagnetic?
(At. nos. Ce = 58, Sm = 62, Eu = 63, Yb= 70)

  • Ce2+

  • Sm2+

  • Eu2+

  • Yb2+


693.

Platinum, palladium and iridium are called noble metals because:

  • Alfred Nobel discovered them

  • they are shining lustrous and pleasing to look at

  • they are found in native state

  • they are inert towards many common reagents


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694.

Cupric compounds are more stable than their cuprous counterparts in solid state. This is because

  • the endothermic character of the 2nd IP of Cu is not so high

  • size of Cu2+ is less than Cu+

  • Cu2+ has stable electronic configuration as compared to Cu+

  • the lattice energy released for cupric compounds is much higher than Cu+


A.

the endothermic character of the 2nd IP of Cu is not so high

B.

size of Cu2+ is less than Cu+

D.

the lattice energy released for cupric compounds is much higher than Cu+

Electronic configuration of cuprous (Cu+) and cupric (Cu2+) ions are as follows-

Cu+ = [Ar] 3d104s0

Cu2+ = [Ar] 3d94s0

Electronic configuration of Cu+ is more stable as compared to Cu2+. It is because in Cu2+(small size) the nuclear charge is sufficient to hold 27 electrons whereas in Cu+ such condition is not possible.

Further, the IInd IP of Cu is not very high as compared to its Ist IP. Consequently a large amount of lattice energy is released for cupric compounds as compared to Cu+  compounds.


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 Multiple Choice QuestionsShort Answer Type

695.

Explain briefly the cause of Lanthanoid contraction.


 Multiple Choice QuestionsMultiple Choice Questions

696.

Anhydrous ferric chloride is prepared by:

  • dissoving Fe(OH)3 in concentrated HCl

  • dissolving Fe(OH)3 in dilute HCl

  • passing dry HCl overheated iron scrap

  • passing dry Cl2 gas overheated iron scrap


697.

For which element the inertness of the electron pair will not be observed? 

  • Sn

  • Fe

  • Pb

  • In


698.

Composition of azurite mineral is

  • CuCO3.CuO

  • Cu(HCO3)2.Cu(OH)2

  • 2CuCO3.Cu(OH)2

  • CuCO3.2Cu(OH)2


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699.

When H2S gas is passed in a metal sulphate solution in presence of NH4OH, a white precipitate is produced. The metal is identified as:

  • Zn

  • Fe

  • Pb

  • Hg


700.

Which of the following is philosopher's wool ?

  • ZnO

  • HgO

  • Ag2O

  • CuO


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