Explain briefly the cause of Lanthanoid contraction. from Chemis

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 Multiple Choice QuestionsMultiple Choice Questions

691.

Which of the following does not give oxygen on heating?

  • KClO3

  • Zn(ClO3)2

  • K2Cr2O7

  • (NH4)2Cr2O7


692.

Which ofthe following lanthanoid ions is diamagnetic?
(At. nos. Ce = 58, Sm = 62, Eu = 63, Yb= 70)

  • Ce2+

  • Sm2+

  • Eu2+

  • Yb2+


693.

Platinum, palladium and iridium are called noble metals because:

  • Alfred Nobel discovered them

  • they are shining lustrous and pleasing to look at

  • they are found in native state

  • they are inert towards many common reagents


694.

Cupric compounds are more stable than their cuprous counterparts in solid state. This is because

  • the endothermic character of the 2nd IP of Cu is not so high

  • size of Cu2+ is less than Cu+

  • Cu2+ has stable electronic configuration as compared to Cu+

  • the lattice energy released for cupric compounds is much higher than Cu+


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 Multiple Choice QuestionsShort Answer Type

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695.

Explain briefly the cause of Lanthanoid contraction.


On moving in the lanthanoid series from left to right successive electrons enter into ante penultimate 4f-subshell which imparts very poor shielding effect (due to its diffused nature), hence effective nuclear charge gradually increases with increase in atomic number. That is why shrinkage is observed on moving through lanthanide series, this is known as lanthanide contraction.


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 Multiple Choice QuestionsMultiple Choice Questions

696.

Anhydrous ferric chloride is prepared by:

  • dissoving Fe(OH)3 in concentrated HCl

  • dissolving Fe(OH)3 in dilute HCl

  • passing dry HCl overheated iron scrap

  • passing dry Cl2 gas overheated iron scrap


697.

For which element the inertness of the electron pair will not be observed? 

  • Sn

  • Fe

  • Pb

  • In


698.

Composition of azurite mineral is

  • CuCO3.CuO

  • Cu(HCO3)2.Cu(OH)2

  • 2CuCO3.Cu(OH)2

  • CuCO3.2Cu(OH)2


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699.

When H2S gas is passed in a metal sulphate solution in presence of NH4OH, a white precipitate is produced. The metal is identified as:

  • Zn

  • Fe

  • Pb

  • Hg


700.

Which of the following is philosopher's wool ?

  • ZnO

  • HgO

  • Ag2O

  • CuO


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