Why does oxygen not show an oxidation state of + 4 and + 6 like s

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 Multiple Choice QuestionsShort Answer Type

431. The tendency to show-2 oxidation state diminishes from S to Po. Why?
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432. Why does oxygen not show an oxidation state of + 4 and + 6 like sulphur?


The electronic configuration of oxygen is 1s2 2s2 2px2 2py12pz1 i.e. it has two half-filled orbital and there is no d-orbital available for excitation of electron. Further, it is the most electronegative element of its family. Hence it shows oxidation state -2 only. Other elements like sulphur have d-orbital available for excitation, thereby giving four and six half-filled orbitals; moreover they can combine with more electronegative elements. Hence they shows oxidation states of +2,+4 and +6 also.

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433. Give one example each of the oxoacids of phosphorus in which the P has the oxidation state of (i) + 4 (ii) + 3.
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434. Name all the elements of group 16. Which elements is radioactive?
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435. Why are group 16 elements called chalcogens?
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436. Give two important uses of Selenium.
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437. Name two allotrope of sulphur. Which allotrope is stable at room temperature?
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438. Which allotrope of selenium coducts electricity?
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439. Why does sulphur in vapour state exhibit paramagnetic behaviour?
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440. Why are group 16 elements called polymorphic elements?
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