In qualitative analysis, in III group NH4Cl is added before NH4OH

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1081.

The element having highest electron affinity is :

  • bromine

  • iodine

  • fluorine

  • chlorine


1082.

The correct order according to size is :

  • O > O- > O2-

  • O- > O2- >O

  • O2- >O- > O

  • O > O2- >O-


1083.

pH of a 0.0001M HCl solution is

  • 4.0

  • 2.0

  • 6.0

  • 7.0


1084.

Pb reacts with dilute HNO3 produces:

  • NO

  • NH4NO3

  • N2O5

  • NO2


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1085.

End-product of the hydrolysis of XeF6 is:

  • XeF4O

  • XeF2O2

  • XeO3

  • XeO3-


1086.

Aqueous solution of ferric chloride is acidic due to

  • ionization

  • polarization

  • dissociation

  • hydrolysis


1087.

The correct order of heat of formation of halogen acids is

  • HI > HBr > HCl > HF

  • HF > HCl > HBr > HI

  • HCl > HF > HBr > HI

  • HCl > HBr > HF > HI


1088.

The hydroxide insoluble in NH4OH + NH4Cl is

  • Al(OH)3

  • Ca(OH)3

  • Zn(OH)2

  • Mg(OH)2


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1089.

Precipitate of AgCl is soluble in liquid NH3 the compound forms

  • Ag(NH4)2OH

  • Ag(NH4)2Cl

  • Ag(NH3)2OH

  • Ag(NH3)2Cl


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1090.

In qualitative analysis, in III group NH4Cl is added before NH4OH because

  • to increase the concentration of NH4+ ions

  • to increase the concentration of Cl- ions

  • to reduce the concentration of OH- ions

  • to increase the concentration of OH- ions


C.

to reduce the concentration of OH- ions

In the presence of strong electrolyte, degree of dissociation of weake electroylte ( having common on) gets suppressed due to common ion effect.

NH4Cl being a strong electrolyte, dissociates asNH4Cl  NH4+ + Cl- and NH4OH asNH4OH  NH4+ +OH-

Due to the presence of common ion, the degree of dissociation of NH4OH decrease. Thus, less
OH- ions are produced which are sufficient only for the precipitation of hydroxides of III group
radicals and not ofhigher group radicals.


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