What is meant by the diagonal relationship of elements? Discuss

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 Multiple Choice QuestionsShort Answer Type

171.

How would you explain that BaO is insoluble but BeSO4 is soluble in water?

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172. Explain why halides of beryllium fume in moist air but other alkaline earth metal halides do not.
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 Multiple Choice QuestionsLong Answer Type

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173.

What is meant by the diagonal relationship of elements? Discuss the diagonal relationship of beryllium with aluminium.

Or

Beryllium exhibits some similarities with aluminium. Point out three such properties.


When an element shows similarities to another element in the next higher group, and in the next period, these are said to exhibit diagonal relationship. For example, Li resembles Mg, Be resembles Al and B resembles Si.


Diagonal relationship of beryllium with aluminium:
Since beryllium (Be2+) and aluminium (Al3+) have similar charge/radius ratio, they exhibit diagonal relationship. They resemble as follows:
(i) Both these elements dissolve in strong alkalies to liberate hydrogen and forming beryllate's and aluminates.
                   

(ii) Both have strong tendency to form covalent compounds. Both BeCl2 and AlCl3 are covalent.
(iii) Both form non-volatile, hard oxides (BeO and Al2O3) having very high melting points.

(iv) Both Be and Al form fluoro-complex anions 


(v) Carbides of both the metals react with water liberating methane gas.

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174.

Discuss the diagonal realtionship of Be and Al with regard to:
(i) action of alkali    (ii) structure of chlorides.

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 Multiple Choice QuestionsShort Answer Type

175.

Give any three points of similarities between beryllium and aluminium and two points of dissimilarities between beryllium and barium ?

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176.

How beryllium chloride is prepared? Give its two important properties

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177.

Name the gases in which magnesium wire continues to burn and write the reactions ?

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 Multiple Choice QuestionsLong Answer Type

178.

Draw the structure of: (i) BeCl2 (vapour) (ii) BeCl2 (solid).

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179.

How does magnesium occur in nature? How is magnesium obtained by electrolysis method ?

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180.

What happens when:
(i) magnesium is heated with water.
(ii) magnesium is heated in an atmosphere of carbon dioxide,
(iii) magnesium is treated with dilute sulphuric acid and
(iv) magnesium is treated with nitrogen?

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