Important Questions of Thermodynamics Chemistry | Zigya

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 Multiple Choice QuestionsShort Answer Type

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221.

Estimate the enthalpy change for the reaction:

straight H subscript 2 left parenthesis straight g right parenthesis space plus space Br subscript 2 left parenthesis straight g right parenthesis space rightwards arrow space space 2 HBr left parenthesis straight g right parenthesis

Given that bond enthalpy of H – H, Br – Br and H – Br bonds are 435 kJ mol–1, 192 kJ mol–1 and 368 kJ mol–1 respectively.

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222.

Calculate increment subscript straight r straight H to the power of 0 of tge reaction


The average bond enthalpies of C – H bond and C – Cl bond are 415 kJ mol
–1 and 326 kJ mol–1 respectively.

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223.

Compute the enthalpy of hydrogenation of ethylene if the bond enthalpies of H – H, C – H, C – C and C = C bonds are 436, 485, 347 and 619 kJ mol–1 respectively.

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 Multiple Choice QuestionsLong Answer Type

224.

Calculate increment subscript straight r straight H to the power of 0 for the reaction 

The bond enthalpies of C - H,  O = O, C = O,  O - H and C = C bonds are 414, 499, 460 and 619 kJ mol-1 respectively. 

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225. Calculate the enthalpy change for the process
CCl subscript 4 left parenthesis straight g right parenthesis space rightwards arrow space space straight C left parenthesis straight g right parenthesis space plus space 4 Cl left parenthesis straight g right parenthesis
and calculate the bond enthalpy of C - Cl in CCl4(g).
  space increment subscript vap straight H to the power of 0 left parenthesis CCl subscript 4 right parenthesis space equals space 30.5 space kJ space mol to the power of negative 1 end exponent
space increment subscript straight f straight H to the power of 0 left parenthesis CCl subscript 4 right parenthesis space equals space minus 135.5 space kJ space mol to the power of negative 1 end exponent
space increment subscript straight a straight H to the power of 0 left parenthesis straight C right parenthesis space equals space 715.0 space kJ space mol to the power of negative 1 end exponent comma
where increment subscript straight a straight H to the power of 0 is enthalpy of atomisation and increment subscript straight a straight H to the power of 0 left parenthesis Cl subscript 2 right parenthesis space equals space 242 space kJ space mol to the power of negative 1 end exponent
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226. Calculate the C – C bond energy from the following data:

left parenthesis straight i right parenthesis space 2 straight C left parenthesis graphite right parenthesis space plus space 3 straight H subscript 2 left parenthesis straight g right parenthesis rightwards arrow space space straight C subscript 2 straight H subscript 6 left parenthesis straight g right parenthesis semicolon space space space increment straight H space equals space minus 84.67 space kJ
left parenthesis ii right parenthesis space straight C left parenthesis graphite right parenthesis space space rightwards arrow space space straight C left parenthesis straight g right parenthesis semicolon space space space increment straight H space equals space 716.7 space kJ
left parenthesis iii right parenthesis space straight H subscript 2 left parenthesis straight g right parenthesis space space space rightwards arrow space space 2 straight H left parenthesis straight g right parenthesis semicolon space space space increment straight H space equals space 435.9 space kJ
Assume 416 kJ as the C - H bond energy, Express it in kJ mol-1.
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227.

What do you mean by calorific value of foods and fuels?

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228.

The enthalpies of combustion of methane and ethane are –890.3 and –1559.7 kJ mol–1 respectively. Which of the two has a greater efficiency of the fuel per gram?

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229. Thermochemical equation for two rocket fuels are given below:

2 space Al left parenthesis straight s right parenthesis space plus space 1 1 half straight O subscript 2 left parenthesis straight g right parenthesis space space rightwards arrow space space space Al subscript 2 straight O subscript 3 left parenthesis straight s right parenthesis semicolon
space space increment subscript straight r straight H to the power of 0 space equals space minus 1667.8 space kJ
straight H subscript 2 left parenthesis straight g right parenthesis space plus space 1 half straight O subscript 2 left parenthesis straight g right parenthesis space space space rightwards arrow space space space straight H subscript 2 straight O left parenthesis straight l right parenthesis semicolon space
increment subscript straight r straight H to the power of 0 space equals space minus 285.9 space kJ

If equal masses of aluminium and hydrogen are used, which is better rocket fuel?

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 Multiple Choice QuestionsShort Answer Type

230. Define lattice enthalpy. How is it relate to the stability of an ionic compound?
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