Given:What is the standard enthalpy of formation of NH3 gas? f

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 Multiple Choice QuestionsShort Answer Type

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191.

Given:
straight N subscript 2 left parenthesis straight g right parenthesis space plus space 3 straight H subscript 2 left parenthesis straight g right parenthesis space rightwards arrow space space 2 NH subscript 3 left parenthesis straight g right parenthesis semicolon
space space space space space space space space space space space space space space space space space space increment subscript straight r straight H to the power of 0 space equals space minus 92.4 space kJ space mol to the power of negative 1 end exponent
What is the standard enthalpy of formation of NH3 gas?


The enthalpy of formation of ammonia is the enthalpy change for the formation of 1 mole of ammonia from its elements.
Given that enthalpy of formation for 2 moles of NH3 = –92.4 kJ

Therefore, standard enthalpy of formation for


Hence standard enthalpy of formation for NH3
  

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192.

Calculate the heat of reaction 
CH subscript 4 left parenthesis straight g right parenthesis space plus space 4 Cl subscript 2 left parenthesis straight g right parenthesis space rightwards arrow space space space space CCl subscript 4 left parenthesis straight g right parenthesis space plus space 4 HCl left parenthesis straight g right parenthesis if the heats of formation of CH subscript 4 left parenthesis straight g right parenthesis comma space Cl subscript 2 left parenthesis straight g right parenthesis comma space CCl subscript 4 left parenthesis straight g right parenthesis space and space HCl left parenthesis straight g right parenthesis space are comma space
space space minus 74.9 comma space space 0.0 comma space space minus 139.0 space and space minus 92.3 space kJ space mol to the power of negative 1 end exponent respectively.

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193.

Calculate the enthalpy change for the reaction:

CO subscript 2 left parenthesis straight g right parenthesis space plus space straight H subscript 2 left parenthesis straight g right parenthesis space rightwards arrow space space CO left parenthesis straight g right parenthesis space plus space straight H subscript 2 straight O left parenthesis straight g right parenthesis
given space that space increment straight H subscript straight f superscript degree space for space CO subscript 2 left parenthesis straight g right parenthesis comma space CO left parenthesis straight g right parenthesis space and space straight H subscript 2 straight O left parenthesis straight g right parenthesis space
are space minus 395.5 comma space minus 113.3 space and space minus 241.8 space kJ space mol to the power of negative 1 end exponent
respectively.

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194.

Calculate the enthalpy change of reaction:
4 NH subscript 3 left parenthesis straight g right parenthesis space plus space 3 straight O subscript 2 left parenthesis straight g right parenthesis space space rightwards arrow space space space 6 straight H subscript 2 straight O left parenthesis straight l right parenthesis space plus 2 straight N subscript 2 left parenthesis straight g right parenthesis at 298K, given that the enthalpies of formation at 298 K for NH subscript 3 left parenthesis straight g right parenthesis space and space straight H subscript 2 straight O left parenthesis straight l right parenthesis space are space comma
minus 46.0 space and space minus 286.0 space kJ space mol to the power of negative 1 end exponent space respectively. space

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195.

Enthalpies of formation of CO(g), CO2(g), N2O(g) and N2O4 (g) are -110, -393, 81 and 9.7 kJ mol-1. Find the value of space increment subscript straight r straight H to the power of 0 for the reaction:
N2O4 (g) + 3CO(g)   space rightwards arrow  N2O(g) + 3CO2(g)

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 Multiple Choice QuestionsLong Answer Type

196.

The combustion of one mole of benzene takes place at 298K and 1 atm. After combustion, CO2(g) and H2O(l) are produced and 3267.0 kJ of heat is liberated. Calculate the standard enthalpy of formation of ∆fH° benzene, given that standard enthalpy of formation of CO2(g) and H2O(l) are –393.5 kJ mol–1 and –285.83 kJ mol–1respectively.

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 Multiple Choice QuestionsShort Answer Type

197.

Define enthalpy of neutralization.

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 Multiple Choice QuestionsLong Answer Type

198.

Explain why enthalpy of neutralization of a strong acid and strong base remains the same and the value changes if one of them is weak.

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199.

Explain the following:
(i) Enthalpy of fusion
(ii) Enthalpy of vaporization
(iii) Enthalpy of sublimation.

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 Multiple Choice QuestionsShort Answer Type

200.

Differentiate between change of state and phase change.

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