111.

CH₃Br + KCN (alc) → X $\underset{\mathrm{Na}/ {\mathrm{C}}_2{\mathrm{H}}_5\mathrm{OH}}{\overset{\mathrm{Reduction}}{\to }}$ Y

What is Y in the series?

• CH₃CN

• C₂H₅CN

• C₂H₅NH₂

• CH₃NH₂

Acetonitrile on reduction gives

• propanamine

• methanamine

• ethanamine

• None of these

Methyl amine reacts with methyl iodide. For completion of reaction, how many moles of methyl iodide are required ?

• 1

• 2

• 3

• 4

Complete the following reaction
RNH₂ + H₂SO₄   →

• [RNH₃]⁺HSO^-₄

• $[{\mathrm{RNH}}_3{]}_2^{+}{\mathrm{SO}}_4^{2-}$

• RNH₂.H₂SO₄

• no reaction

Primary amine (RNH₂) reacts with nitrous acid to give

• ${\mathrm{RNH}}_3^{+}{\mathrm{NO}}_2$

• ROH

• ROR

• None of these

IUPAC name of CH₃—CHNH₂—CH₃ is

• dimethyl amine

• 2-amino propane

• isopropylamine

• 2-propanamine

Aniline reacts with acetaldehyde to form

• Schiffs base

• carbylamine

• immine

• none of these

In the following reaction, X and Y are respectively

CH₃COOH + NH₃ → X $\stackrel{∆}{\to }$ Y + H₂O

• CH₃CONH₂, CH₄

• CH₃COONH₄, CH₃CONH₂

• CH₃CONH₂, CH₃COOH

• CH₃NH₂, CH₃CONH₂

Which one of the following is the molecular formula of a tertiary amine ?

• C₂H₇N

• C₃H₉N

• CH₅N

• CH₃N

Aniline is not the major product in one of the following reactions. Identify that reaction

• ${\mathrm{C}}_6{\mathrm{H}}_5\mathrm{OH} + {\mathrm{NH}}_3 \underset{300°\mathrm{C}}{\overset{ {\mathrm{ZnCl}}_2}{\to }}$

• ${\mathrm{C}}_6{\mathrm{H}}_5{\mathrm{NO}}_2 + \mathrm{Zn} \mathrm{powder}\hspace{0.17em}\stackrel{\mathrm{alcoholic} \mathrm{KOH}}{\to }$

• ${\mathrm{C}}_6{\mathrm{H}}_5\mathrm{Cl} +{\mathrm{NH}}_3 \underset{{\mathrm{Cu}}_2\mathrm{O}}{\overset{ 200°\mathrm{C}}{\to }} \mathrm{high} \mathrm{pressure}$

• ${\mathrm{C}}_6{\mathrm{H}}_5{\mathrm{NO}}_2 + 6\left(\mathrm{H}\right) \underset{\mathrm{HCl}}{\overset{\mathrm{Fe} +{\mathrm{H}}_2\mathrm{O}}{\to }}$