Which of the following compounds will give red colour on Lassaign

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181.

Which of the following compounds will give red colour on Lassaigne test?

  • NaCNS

  • NH2CSNH2 (thiourea)

  • p-NH2C6H4SO3H (p- aminobenzene sulphonic acid)

  • all of the above


D.

all of the above

When nitrogen and sulphur both are present in the organic compound, they combine during fusion to form sodium thiocyanate (sulphocyanide). This when heated with FeSO4 or FeCl3, produces a red blood colouration due to ferric thiocyanate (or sulphocyanide). Thus, thiourea and p-aminobenzene sulphonic acid give red colour on lassaigne test.

Na + C + S + N  NaSCN(sodium thiocyanate or sodium sulphocyanide)Fe3+ + 3NaSCN  Fe(SCN)3ferric thiocyanate                             (ferric sulphocyanide)                             (blood red colouration)


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182.

A positive carbylamine test is given by

I. N, N-dimethylaniline

II. 2, 4-dimethylamine

III. N-methyl-o-methylaniline

IV. p-methylbenzyl amine

  • (II) and (IV)

  • (I) and (IV)

  • (II) and (III)

  • (I) and (II)


183.

Wat will be the final product of following reaction sequence?


184.

The IUPAC name of the following compound is

 

  • 2-carbamoylhexanal

  • 2-carbamoylhex-3-enal

  • 2-methyl-6-oxohex-3-enamide

  • 6-keto-2-methyl hexamide


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185.

Which one of the following is the correct structure of sulphapyridine?


186.

Iidentify Z in the following reaction:


187.

H3CCONH2 + Br2 + 4 NaOH  Y + Na2CO3+ 2NaBr + 2H2O

  • H3CCH2NH2

  • H3CNH2

  • H3CCOBr

  • HCONH2


188.

Which is the strongest base among the following?

  • H3CNH2


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189.

Cyclohexylamine and aniline can be distinguished by

  • Hinsberg test

  • Carbylamine test

  • Lassaigne test

  • Azo dye test


190.

Nitration of phenyl benzoate yields the product


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