A positive carbylamine test is given byI. N, N-dimethylanilineII.

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 Multiple Choice QuestionsMultiple Choice Questions

181.

Which of the following compounds will give red colour on Lassaigne test?

  • NaCNS

  • NH2CSNH2 (thiourea)

  • p-NH2C6H4SO3H (p- aminobenzene sulphonic acid)

  • all of the above


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182.

A positive carbylamine test is given by

I. N, N-dimethylaniline

II. 2, 4-dimethylamine

III. N-methyl-o-methylaniline

IV. p-methylbenzyl amine

  • (II) and (IV)

  • (I) and (IV)

  • (II) and (III)

  • (I) and (II)


A.

(II) and (IV)

Carbylamine or isocyanide test is given by only primary amines, whether they are aliphatic or aromatic.

I, II and III are aromatic but compound IV is an aliphatic amine. Further, compound I is tertiary amine, II and IV are primary amines, thus give positive carbylamine test, whereas compound III is a secondary amine.


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183.

Wat will be the final product of following reaction sequence?


184.

The IUPAC name of the following compound is

 

  • 2-carbamoylhexanal

  • 2-carbamoylhex-3-enal

  • 2-methyl-6-oxohex-3-enamide

  • 6-keto-2-methyl hexamide


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185.

Which one of the following is the correct structure of sulphapyridine?


186.

Iidentify Z in the following reaction:


187.

H3CCONH2 + Br2 + 4 NaOH  Y + Na2CO3+ 2NaBr + 2H2O

  • H3CCH2NH2

  • H3CNH2

  • H3CCOBr

  • HCONH2


188.

Which is the strongest base among the following?

  • H3CNH2


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189.

Cyclohexylamine and aniline can be distinguished by

  • Hinsberg test

  • Carbylamine test

  • Lassaigne test

  • Azo dye test


190.

Nitration of phenyl benzoate yields the product


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