Among the following, the compound that contains ionic, covalent and co-ordinate linkage is
NH3
NH4Cl
NaCl
CaO
A covalent molecule AB3 has pyramidal structure. The number of lone pair and bond pair of electrons in the molecule are respectively
2 and 2
0 and 4
3 and 1
1 and 3
The magnetic moment of a transition metal ion is BM. Therefore, the number of unpaired electrons present in it is
3
4
1
2
Which one of the following conversions involve change in both hybridisation and shape?
CH4 → C2H6
NH3 → NH
BF3 → BF
H2O → H3O+
Peroxide ion ......
(i) has five completely filled antibonding molecular orbitals
(ii) is diamagnetic
(iii) has bond order one
(iv) is isoelectronic with neon
Which one of these is correct?
(ii) and (iii)
(i), (ii) and (iv)
(i), (ii) and (iii)
(i) and (iv)
When O2 is converted into O
both paramagnetic character and bond order increase
bond order decreases
paramagnetic character increases
paramagnetic character decreases and the bond order increases
D.
paramagnetic character decreases and the bond order increases
When O2 is converted into O paramagentic character decreases and the bond order increases.
(i) O2 - (σ1s)2 (σ*1s)2 (σ2s)2 (σ*2s)2 (σ2pz)2 (2px)2 (2py)2 (*2px)1 (*2py)1
Bond order = = 2
O2 molecule having 2 unpaired electron.
(ii) O - (σ1s)2 (σ*1s)2 (σ2s)2 (σ*2s)2 (σ2pz)2 (2py)2 (*2px)1 (*2py)0
Bond order = = 2.5
ion having only 1 unpaired electron.
Increasing order of carbon-carbon bond length for the following is
C < B < A < D
B < C < A < D
D < C < A < B
B < A < C < D
Hybridised states of carbon in graphite and diamond are respectively
sp3, sp3
sp3, sp2
sp2, sp2
sp2 , sp3
Which of the following is not a characteristic of a covalent compound?
No definite geometry
Insoluble in polar solvent
Smal difference in electronegativity between the combining atoms
Low melting point