In which of the following molecules the central atom does not have sp3 hybridisation?
CH4
SF4
BF4-
BF4-
From the following bond energies:
H-H bond energy: 431.37 kJ mol-
C=C bond energy: 606.10 kJ mol-
C- C bond energy: 336.49 kJ mol-
C-H bond energy: 410.50 kJ mol-
Enthalpy for the reaction,
will be
1523.6 kJ mol-
-243.6 kJ mol-
-1200. kJ mol-
-1200. kJ mol-
According to MO theory which of the following lists ranks the nitrogen species in terms of increasing bond order?
The state of hybridization of C2, C3, C5 and C6 of the hydrocarbon,
is in the following sequence
sp, sp3, sp2 and sp3
sp3, sp2, sp2 and sp
sp,sp2,sp2 and sp3
sp,sp2,sp2 and sp3
In which of the following molecules/ions BF3, NO2-, NH2- and H2O, the central atom is sp2 hybridised?
NO2- and NH2-
NH2- and H2O
NO2- and H2O
NO2- and H2O
The angular shape of ozone molecule (O3) consists of
1 sigma and 2 pi bonds
2 sigma and 2 pi bonds
1 sigma and 1 pi bonds
1 sigma and 1 pi bonds
The correct order of increasing bond angles in the following triatomic species is
B.
As the number of lone pair of electrons increases, bond angle decreases. NO2+ ion is isoelectronic with the CO2 molecule. It is a linear ion and its central atom (N+) undergoes sp-hybridisation, hence bond angle is 180o.
In NO2- ion, N -atom undergoes sp2 hybridisation. The angle between hybrid orbital should be 120o but one lone pair of electrons is lying on N- atom, hence bond angle decreases to 115o.
In NO2 molecule, N -atom has one unpaired electron in a sp2-hybrid orbital. The bond angle should be 120o but actually, it is 132o. It may be due to one unpaired electron in a sp2-hybrid orbital.
Therefore, the increasing order of bond angles.
Four diatomic solutions of the following were prepared in water separately. Which one of the solutions will record the highest pH?
Bond dissociation enthalpy of H2, Cl2 and HCl and 434, 242 and 431 kJ mol-1 respectively. Enthalpy of formation of HCl is
93 kJ mol-1
-245 kJ mol-1
-39 kJ mol-1
-39 kJ mol-1
In the hydrocarbon
The state of hybridization of carbon 1, 3, and 5 are in the following sequence
sp2, sp, sp3
sp, sp3, sp2
sp, sp2, sp3
sp, sp2, sp3