Multiple Choice QuestionsWhich one of the following does not exhibit geometrical isomerism?
Octahedral complex with formula [MX2L4]
Square planar complex with formula [MX2L2]
Tetrahedral complex with formula [MAB XL]
Octahedral complex with formula [MX2(L -L)2]
Which of the following metal ions has a calculated magnetic moment value of ✓24. BM?
Mn2+
Fe2+
Fe3+
Co2+
The pair of metal carbonyl complexes that are isoelectronic is
Ni(CO)4 and V(CO)6
[Cr(CO)6] and V(CO)6
[Fe(CO)4]- and Cr(CO)6
[Co(CO)4]- and Ni(CO)4
The compound that inhibits the growth of tumors is:
trans-[Pt(Cl)2(NH3)2]
trans-[Pd(Cl)2(NH3)2]
cis-[Pd(Cl)2(NH3)2]
cis-[Pt(Cl)2(NH3)2]
The calculated spin–only magnetic moments (BM) of the anionic and cationic species of [Fe(H2O)6]2 and [Fe(CN)6], respectively, are :
4.9 and 0
2.84 and 5.92
0 and 5.92
0 and 4.9
The number of water molecules not coordinated to copper ion directly in CuSO4.5H2O is
2
3
1
4
C.
1
In CuSO4.5H2O, four water molecules are coordinated to Cu2+ ion and one water molecule is outside the coordinate sphere. Therefore, the number of water molecule coordinated to copper ion is 3.
The species that can have a trams-isomer (en=ethane-1,2-diamine,ox=oxalate)
[Cr(en)2(ox)]+
[Pr(en)2Cl2]2+
[Zn(en)Cl2]
[Pt(en)Cl2]
The INCORRECT statement is :
The gemstoe, ruby has Cr3+ ions occupying the octahedral sites of beryl
The spin – only magnetic moments of [Fe(H2O)6]2+ and [Cr(H2O)6]2+ are nearly similar.
The color of [CoCl(NH3)5]2+ is violet as it absorbs the yellow light.
The spin only – magnetic moment of [Ni(NH3)4(H2O2)]2+ is 2.83 BM.
The crystal field stabilization energy (CFSE) of [Fe(H2O)6]Cl2 and K2[NiCl4], respectively are:
-2.4 Δ0 and -1.2Δt
-0.4 Δ0 and -1.2Δt
-0.6 Δ0 and -0.8Δt
-0.4 Δ0 and -0.8Δt
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