Following compounds are given
(i) CH3CH2OH
(ii) CH3COCH3
(iii)
(iv) CH3OH
Which of the above compound(s) on being warmed with iodine solution and NaOH, will give iodoform?
(i), (iii) and (iv)
Only (ii)
(i), (ii) and (iii)
(i) and (ii)
A dihaloalkane 'X, having formula C3H6Cl2, on hydrolysis gives a compound, that can reduce Tollen's reagent. The compound 'X' is
1, 2-dichloropropane
1, 1-dichloropropane
1, 3-dichloropropane
2, 2-dichloropropane
B.
1, 1-dichloropropane
Since, the obtained compound reduces Tollen's reagent, it must be an aldehyde. Thus, it is obvious that both the -Cl atoms are present at C1. Hence, the compound 'X' is 1, 1-dichloropropane and the reactions are as follows-
Chloroform on reduction with zinc dust and water gives
methyl chloride
dichloro methane
chloro methane
methane
How many isomeric vicinal-dihalides are possible for the compound having molecular formula C3H6Cl2 ?
1
2
3
4
The IUPAC name of the compound is
1-bromo-1-chloro-4, 4'-bicyclobutane
4-( 4'-chlorocyclobutyl)-1-bromocyclobutane
3-bromo-3'-chloro-1, 1-bicyclobutane
4-(4'-bromocyclobutyl)-1-chlorocyclo butane