Chlorobenzene is o, p-directing in electrophilic substitution reaction. The directing influence is explained by
+M of Ph
+I of Cl
+M of Cl
-I of Ph
CH3MgBr + CH2 = CH-COH Product
It is (1 : 4 addition)
CH2=CH-
CH2OH-CH=CH-CH3
CH3CH2CH2CHO
None of the above
Which one is least reactive in a nucleophilic substitution reaction?
CH3CH2Cl
CH2=CHCH2Cl
CH2=CHCl
(CH3)3CCl
The number of moles of Grignard reagent consumed per mole of the compound
2
3
1
4
D.
4
Grignard reagent (RMgX) will attack on C-O bond of the given compound. As there are 4-C-O bonds in the given compound, thus four moles of Grignard reagent consumed per mole of the given compound.
Among the given compound choose the two i.hat yield same carbocation on ionisation.
(ii) and (iv)
(i) and (ii)
(ii) and (iii)
(i) and (iii
An organic compound neither reacts neutral ferric chloride solution nor with Fehling solution. It however, reacts with Grignard reagent and gives positive iodoform test. The compound is: