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 Multiple Choice QuestionsMultiple Choice Questions

111.

Reduction of nitrobenzene with Zn and alcoholic KOH solution results in the formation of the following compound.

  • hydrazobenzene

  • azobenzene

  • aniline

  • phenylhydroxylamine


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112.

Nitrobenzene on reduction using zinc in alkaline medium results in X. The number of sigma (σ) and pi (π) bonds in X is-

  • 24 σ, 7 π

  • 24 σ, 6 π

  • 27 σ, 7 π

  • 24 σ, 6 π


D.

24 σ, 6 π

Nitrobenzene on reduction using zinc in alkaline medium gives hydrazobenzene. It consists of 27 σ and 6 π bonds.


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113.

Identify A and B in the following reactions

 


114.

Which of the following statements is not correct?

  • The six carbons in benzene are sp2 hybridised.

  • Benzene has (4n + 2) Π electrons.

  • Benzene undergoes substitution reactions

  • Benzene has two carbon-carbon bond lengths, 1.54 Å and 1.34 Å.


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115.

The chlorination of ethane is an example for which type of the following reactions ?

  • Nucleophilic substitution

  • Electrophilic substitution

  • Free radical substitution

  • Rearrangement


116.

C2H6 450°C C2H4 + H2

Above reaction is known as

  • combustion

  • rearrangement

  • pyrolysis

  • cleavage


117.

Which one of the following gives sooty flame on combustion?

  • C2H4

  • CH4

  • C2H6

  • C6H6


118.

What is Z in the following reaction?

CH3-CH2-CO2NaNaOH/CaO Z

  • propane

  • n-butane

  • ethane

  • ethyne


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119.

Which of the following reagent is used to find out carbon-carbon multiple bonds?

  • Grignard reagent

  • Baeyer's reagent

  • Sandmeyer's reagent

  • Gatermann reagent


120.

Which one of the following is more readily hydrolysed by SN1 mechanism?

  • (C6H5)2C(CH3)Br

  • C6H5CH2Br

  • C6H5CH(CH3)Br

  • (C6H5)2CHBr


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