An organic alkadiene on reductive ozonolysis produces
(i) acetaldehyde
(ii) acetone
(iii) 2-methylpropane-1,3-dial
The formula of alkadiene will be
CH3C(CH3)=CHCH(CH3)CH=CHCH3
CH3CH(CH3)CH=C(CH3)CH=CHCH3
CH3C(CH3)=CHCHC(CH3)=CHCH3
CH3CH2CH(CH3)CH=CHC(CH3)=CH2
2-chloro-3-methylbutane is treated with sodium in etherial solution, then it will give
2,4-dimethylhexane
3,5-dimethylhexane
2,3,4,5-tetramethylhexane
2,6-dimethyloctane
Which one of the following hydrocarbons has octane number 100?
2, 2, 3-trimethylpentane
2, 3, 3-trimethylpentane
2, 2, 4-trimethylpentane
2, 3, 4-trimethylpentane
Which one of the following is the best reagent to accomplish the following conversion ?
NaBH3
Na|ether
Zn|C2H5OH
Mg followed by H3O+
Propyne and propene can be distinguished by
conc. H2SO4
Br2 in CCl4
dil. H2SO4
AgNO3 in ammonia
D.
AgNO3 in ammonia
Propyne because of the presence of acidic H-atom, reacts with ammoniacal AgNO3 and gives grey/ white silver propynilide. Propene, on the other hand, does not have any acidic H-atom, so it does not react with ammoniacal AgNO3. Hence, these two are separated by this reagent.
CH3C ≡ CH + AgNO3 + NH4OH → CH3C ≡ CAg ↓ + NH4NO3 + H2O
CH3CH ≡ CH2 + AgNO3 + NH4OH → No reaction
C2H5Cl . This method is
Wurtz synthesis
Kolbe synthesis
Corey House synthesis
Friedel-Craft synthesis
One of the isomer of the 5th member of alkyne series is optically active. It is
4-methyl pent-2-yne
3-methyl pent-1-yne
4-methyl pent-1-yne
3, 3-dimethyl but-1-yne